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Question
Calculate the equivalent conductivity of 1 M H2SO4, whose specific conductivity is 26 × 10−2 ohm−1 cm−1.
Numerical
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Solution
Conductivity (κ) = 26 × 10−2 ohm−1 cm−1
Normality (N) = 2 (since 1 M H2SO4 gives 2 equivalents per mole)
To calculate the equivalent conductance (Λeq) of a solution, use the formula:
`Lambda_(eq) = (kappa xx 1000)/N`
= `(26 xx 10^-2 xx 1000)/2`
= `260/2`
= 130 S cm2 eq−1
∴ The equivalent conductance of 1 M H2SO4 solution is 130 S cm2 eq−1.
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