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Assertion: When Ecell∘ is positive, the cell reaction is feasible and proceeds spontaneously. Reason: When Ecell∘ is positive, ΔG° is negative which makes the cell reaction feasible. - Chemistry (Theory)

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Question

Assertion: When \[\ce{E{^{\circ}_{cell}}}\] is positive, the cell reaction is feasible and proceeds spontaneously.

Reason: When \[\ce{E{^{\circ}_{cell}}}\] is positive, ΔG° is negative which makes the cell reaction feasible.

Options

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

MCQ
Assertion and Reasoning
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Solution

If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

Explanation:

When \[\ce{E{^{\circ}_{cell}}}\] is positive, the standard Gibbs free energy change ΔG° is negative \[\ce{(\Delta G^\circ = -nFE{^{\circ}_{cell}})}\]. A negative ΔG° implies that the cell reaction is feasible and proceeds spontaneously.

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Chapter 3: Electrochemistry - ASSERTION-REASON TYPE QUESTIONS [Page 206]

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Nootan Chemistry Part 1 and 2 [English] Class 12 ISC
Chapter 3 Electrochemistry
ASSERTION-REASON TYPE QUESTIONS | Q 5. | Page 206
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