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Assertion: The basic strength of oxides and hydroxides of lanthanoids decrease with increase in atomic number. Reason: The size of cation of lanthanoids increases with increase in atomic number. - Chemistry (Theory)

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Question

Assertion: The basic strength of oxides and hydroxides of lanthanoids decrease with increase in atomic number.

Reason: The size of cation of lanthanoids increases with increase in atomic number.

Options

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

MCQ
Assertion and Reasoning
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Solution

If Assertion is CORRECT but Reason is INCORRECT.

Explanation:

The basic strength of oxides and hydroxides of lanthanoids decreases with an increase in atomic number due to lanthanoid contraction, which causes a decrease in ionic size. However, the reason is incorrect because the size of lanthanoid cations actually decreases, not increases, with an increase in atomic number.

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Chapter 8: d-and ƒ-Block Elements - ASSERTION-REASON TYPE QUESTIONS [Page 505]

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Nootan Chemistry Part 1 and 2 [English] Class 12 ISC
Chapter 8 d-and ƒ-Block Elements
ASSERTION-REASON TYPE QUESTIONS | Q 6. | Page 505
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