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Account for the Following : O-nitrophenol is More Steam Volatile than P-nitrophenol.

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Question

Account for the following : 

o-nitrophenol is more steam volatile than p-nitrophenol.  

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Solution

o-Nitrophenol is steam volatile due to intramolecular hydrogen bonding while p- nitrophenol is less volatile due to intermolecular hydrogen bonding 

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2018-2019 (March) 56/1/1

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