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Question
A radioactive element is half disintegrated in 40 minutes. What is the time required for the decay of 75% of the element?
Numerical
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Solution
Given:
Half-life t1/2 = 40 minutes
We need to find time for 75% decay, i.e., when 25% remains
For a first-order reaction use
`t = 2.303/k log ([A]_0/([A]))`
= `2.303/k log (1/(1 - x))`
Where x = 0.75 (i.e., 75% decay)
∴ `k = 0.693/t_(1//2)`
= `0.693/40`
= 0.017325 min−1
Time for 75% decay
`t = 2.303/0.017325 log (1/0.25)`
= `2.303/0.017325 log (4)`
= `(2.303 xx 0.6021)/0.017325` ...(log 4 = 0.6021)
= `1.3875/0.017325`
t = 80.1 minutes
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