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If the total volume of a simple cubic unit cell is 6.817 × 10-23 cm3, what is the volume occupied by particles in the unit cell?
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Find the number of atoms in the fcc unit cell.
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Calculate the number of unit cells in 0.3 g of a species having density of 8.5 g/cm3 and unit cell edge length 3.25 × 10-8 cm.
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Derive the relationship between density of substance, its molar mass, and the unit cell edge length. Explain how you will calculate the number of particles, and a number of unit cells in x g of metal.
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What type of solutions exhibit positive deviations from Raoult’s law?
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What is enthalpy change and volume change of mixing of two components forming an ideal solution?
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The vapour pressures of pure liquids A and B are 0.600 bar and 0.933 bar respectively, at a certain temperature.
What is the mole fraction of liquid B in the solution when the total vapour pressure of their mixture is 0.8 bar?
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Distinguish between ideal and non-ideal solutions.
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What is the action of atmospheric oxygen on ethers?
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With the help of vapour pressure-temperature curves for solution and solvent, explain why boiling point of solvent is elevated when a nonvolatile solute is dissolved into it.
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The vapour pressure of a pure solvent at a certain temperature is 0.0227 bar. What is the vapour pressure of a solution containing 6 g of solute (M = 60 g/mol) in 50 g of solvent?
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Explain with reasons and diagrams, the positive and negative deviations from Raoult’s law shown by nonideal solutions.
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Write chemical equation of acetyl chloride with ethanol
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Write the preparation of ethanol from methyl magnesium iodide.
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Write the reaction between ethanol and acetic anhydride.
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Explain the fact that in alkyl aryl ethers, the alkoxy group is ring activating and ortho/para directing towards electrophilic aromatic substitution.
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How will you prepare diethyl ether by dehydration of alcohol?
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What are the limitations to prepare ether by this method?
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