Advertisements
Advertisements
प्रश्न
What are non-ideal solutions?
Advertisements
उत्तर
- The solutions which do not obey Raoult’s law over the entire range of concentrations are called non-ideal solutions.
- Liquids whose molecules interact with one another with a force different from the force their own molecules interact with one another produce non-ideal solutions.
- Therefore, when the forces of attraction between molecules A and B differ from those between molecules A-A or B-B, two liquids A and B, create a non-ideal solution.
संबंधित प्रश्न
The vapour pressure of water at 20°C is 17 mm Hg. What is the vapour pressure of solution containing 2.8 g urea in 50 g of water?
A mixture of benzene and toluene contains 30% by mass of toluene. At 30°C, vapour pressure of pure toluene is 36.7 mm Hg and that of pure benzene is 118.2 mm Hg. Assuming that the two liquids form ideal solutions, calculate the total pressure and partial pressure of each constituent above the solution at 30°C.
State Raoult’s law.
Distinguish between ideal and non-ideal solutions.
With the help of vapour pressure-temperature curves for solution and solvent, explain why boiling point of solvent is elevated when a nonvolatile solute is dissolved into it.
The vapour pressure of a pure solvent at a certain temperature is 0.0227 bar. What is the vapour pressure of a solution containing 6 g of solute (M = 60 g/mol) in 50 g of solvent?
Which of the following is NOT nonideal solution?
9 gram anhydrous oxalic acid (mol. wt. = 90) was dissolved in 9.9 moles of water. If vapour pressure of pure water is pf the vapour pressure of solution is ______.
If 1 mole of ____________ is added to 1 dm3 of water, the boiling point of water will decrease.
5.0 g of sodium hydroxide (molar mass 40 g mol-1) is dissolved in little quantity of water and the solution is diluted upto 100 mL. What is the molarity of the resulting solution?
18 g of glucose (C6H12O6) is added to 178.2 g of water. The vapour pressure of water for this aqueous solution at l00°C is ______.
For an ideal binary liquid solution with `"p"_"A"^circ > "P"_"B"^circ`, which is a relation between XA (mole fraction of A in liquid phase) and YA (mole fraction of A in vapour phase) is correct, XB and YB are mole fractions of B in liquid and vapour phase respectively?
Total vapour pressure of a mixture of 1 mole A`("p"_"A"^circ = 150 " torr")` and 2 mole B`("p"_"B"^circ = 240 " torr")` is 200 mm. In this case, ______.
What are ideal and non-ideal solutions?
Explain the variation of vapour pressures with mole fractions of binary solutions of two volatile liquids forming ideal solutions.
State Raoult’s law for solutions containing volatile solutes.
Write the relationship between mole fraction of solvent and vapour pressure of solution.
A mixture of two liquids A and B have vapour pressures 3.4 × 104 Mn-2 and 5.2 × 104 Nm-2. If the mole fraction of A is 0.85, find the vapour pressure of the solution.
