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How will you prepare acetic anhydride from acetic acid?
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Acid anhydride on reaction with primary amine gives compound having a functional group ______.
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Write the consequences of Schottky defect with reasons.
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Derive an expression to calculate molar mass of non-volatile solute by osmotic pressure measurement.
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Write chemical reactions of following reagents on methoxyethane:
dilute H2SO4
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Calculate the pH of buffer solution composed of 0.01 M weak base BOH and 0.02 M of its salt BA. [Kb = 1.8 × 10–5 for weak base]
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Explain metal deficiency defect with examples.
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AgBr shows which type of defect?
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How acetone is converted into propane.
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How propanal is converted into propane.
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Name a compound where Frenkel defect is found.
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Explain the following term:
Substitutional impurity defect
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Explain the following term:
Interstitial impurity defect
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Define Acidic buffer solution.
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Calculate standard Gibbs energy change at 25°C for the cell reaction.
\[\ce{Cd_{(s)} + Sn^{2+}_{ (aq)} -> Cd^{2+}_{ (aq)} + Sn_{(s)}}\]
\[\ce{E^0_{cd}}\] = –0.403 V, \[\ce{E^0_{Sn}}\] = –0.136 V
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How will you determine the molar mass of non-volatile solute by elevation of boiling point?
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Give reason:
Bleaching action of ozone is also called dry bleach.
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Under what conditions ΔH = ΔU?
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Give two examples which undergo Wolf-Kishner reduction.
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The vapour pressure of water is 16.8 mm Hg at a certain temperature. If the vapour pressure of the solution is 16. 78 mm, find the molality of the solution.
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