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The decomposition of hydrocarbon follows the equation
k = `(4.5 xx 10^11 s^-1) e^(-28000 K//T)`
Calculate Ea.
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The decomposition of A into product has value of k as 4.5 × 103 s−1 at 10°C and energy of activation 60 kJ mol−1. At what temperature would k be 1.5 × 104 s−1?
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The rate of a reaction quadruples when the temperature changes from 293 K to 313 K. Calculate the energy of activation of the reaction assuming that it does not change with temperature.
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The rate constant for the first order decomposition of H2O2 is given by the following equation:
log k = 14.34 − 1.25 × 104 K/T
Calculate Ea for this reaction and at what temperature will its half-period be 256 minutes?
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What role does adsorption play in heterogeneous catalysis?
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Give four examples of heterogeneous catalysis.
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Out of C and CO, which is a better reducing agent at 673 K?
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Giving examples, differentiate between ‘roasting’ and ‘calcination’.
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Why copper matte is put in silica lined converter?
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Out of C and CO, which is a better reducing agent for ZnO?
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Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionisation isomers.
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Write the free radical mechanism for the polymerisation of ethene.
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How do antiseptics differ from disinfectants? Give one example of each.
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What is meant by the term ‘broad spectrum antibiotics’? Explain.
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Name a substance which can be used as an antiseptic as well as disinfectant.
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What are the main constituents of dettol?
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What is tincture of iodine? What is its use?
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Arrange the following:
In decreasing order of the pKb values:
C2H5NH2, C6H5NHCH3, (C2H5)2NH and C6H5NH2
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Arrange the following:
In increasing order of basic strength:
C6H5NH2, C6H5N(CH3)2, (C2H5)2NH and CH3NH2
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Arrange the following:
In increasing order of basic strength:
Aniline, p-nitroaniline and p-toluidine
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