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Chemistry
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What should be the correct IUPAC name for diethylbromomethane?

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

The reaction of toluene with chlorine in the presence of iron and in the absence of light yields ______.

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

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Which of the carbon atoms present in the molecule given below are asymmetric?

\[\begin{array}{cc}
\phantom{}\ce{HO}\phantom{.....}\ce{OH}\phantom{..}\ce{H}\phantom{.....}\ce{O}\phantom{..}\\
\phantom{..}\backslash\phantom{.....}|\phantom{....}|\phantom{.....}//\phantom{.}\\
\ce{\overset{a}{C} - \overset{b}{C} - \overset{c}{C} - \overset{d}{C}}\\
\phantom{..}//\phantom{.....}|\phantom{....}|\phantom{....}\phantom{.}\backslash\phantom{...}\\
\phantom{}\ce{O}\phantom{......}\ce{H}\phantom{...}\ce{OH}\phantom{...}\ce{H}\phantom{}\\
\end{array}\]

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Haloalkanes contain halogen atom (s) attached to the sp3 hybridised carbon atom of an alkyl group. Identify haloalkane from the following compounds.

(i) 2-Bromopentane

(ii) Vinyl chloride (chloroethene)

(iii) 2-chloroacetophenone

(iv) Trichloromethane

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Which of the following compounds can be classified as aryl halides?

(i) \[\ce{p-ClC6H4CH2CH(CH3)2}\]

(ii) \[\ce{p-CH3CHCl(C6H4)CH2CH3}\]

(iii) \[\ce{o-BrH2C - C6H4CH(CH3)CH2CH3}\]

(iv) \[\ce{C6H5 - Cl}\]

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Which of the products will be major product in the reaction given below? Explain.

\[\ce{CH3CH = CH2 + HI -> \underset{(A)}{CH3CH2CH2I} + \underset{(B)}{CH3CHICH3}}\]

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Classify the following compound as a primary, secondary and tertiary halide.

2-Bromo-2-methylpropane

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Why can aryl halides not be prepared by reaction of phenol with \[\ce{HCl}\] in the presence of \[\ce{ZnCl2}\]?

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Match the items of Column I and Column II.

  Column I Column II
(i) SN1 reaction (a) vic-dibromides
(ii) Chemicals in fire extinguisher (b) gem-dihalides
(iii) Bromination of alkenes (c) Racemisation
(iv) Alkylidene halides (d) Saytzeff rule
(v) Elimination of HX from alkylhalide (e) Chlorobromocarbons
[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Match the structures of compounds given in Column I with the classes of compounds given in Column II.

  Column I Column II
(i) \[\begin{array}{cc}
\ce{CH3 - CH - CH3}\\
|\phantom{..}\\
\ce{X}\phantom{..}
\end{array}\]
(a) Aryl halide
(ii) \[\ce{CH2 = CH - CH2 - X}\] (b) Alkyl halide
(iii) (c) Vinyl halide
(iv) \[\ce{CH2 = CH - X}\] (d) Allyl halide
[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Benzophenone can be obtained by:

(i) Benzoyl chloride + Benzene + \[\ce{AlCl3}\]

(ii) Benzoyl chloride + Diphenyl cadmium

(iii) Benzoyl chloride + Phenyl magnesium chloride

(iv) Benzene + Carbon monoxide + \[\ce{ZnCl2}\]

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Give the IUPAC names of the following compounds.

 

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Give the IUPAC names of the following compounds.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Give the IUPAC names of the following compounds.

\[\begin{array}{cc}
\ce{CH3 - CH2 - C - CH2 - CHO}\\
||\phantom{.}\\
\ce{O}\phantom{.}
\end{array}\]

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Give the IUPAC name of the following compound.

CH3 − CH = CH − CHO

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Write IUPAC names of the following structures.

\[\begin{array}{cc}
\ce{CHO}\\
|\phantom{....}\\
\ce{CHO}\\
\end{array}\]

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Write IUPAC names of the following structures.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Write IUPAC names of the following structures.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Arrange the following in decreasing order of their acidic strength and give reason for your answer.

\[\ce{CH3CH2OH, CH3COOH, ClCH2COOH, FCH2COOH, C6H5CH2COOH}\]

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Which of the following is a 3° amine?

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined
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