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Science (English Medium) इयत्ता १२ - CBSE Question Bank Solutions for Chemistry

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Chemistry
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What type of defect can arise when a solid is heated? Which physical property is affected by it and in what way?

[1] Solid State
Chapter: [1] Solid State
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What type of stoichiometric defect is shown by:

(i) ZnS 

(ii) AgBr

[1] Solid State
Chapter: [1] Solid State
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Vapour pressure of water at 293 K is 17.535 mm Hg. Calculate the vapour pressure of water at 293 K when 25 g of glucose is dissolved in 450 g of water.

[1] Solutions
Chapter: [1] Solutions
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In the button cells widely used in watches and other devices, the following reaction takes place:

\[\ce{Zn_{(s)} + Ag2O_{(s)} + H2O_{(l)} -> Zn{^{2+}_{(aq)}} + 2Ag_{(s)} + 2OH^-_{ (aq)}}\]

Determine ΔrG° and E° for the reaction.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Comment on the statement that “colloid is not a substance but a state of substance”.

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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The hexaquo manganese (II) ion contains five unpaired electrons, while the hexacyanoion contains only one unpaired electron. Explain using Crystal Field Theory.

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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Draw figure to show the splitting of d orbitals in an octahedral crystal field.

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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How does the magnitude of Δ0 decide the actual configuration of d orbitals in a coordination entity?

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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The melting points and solubility in water of amino acids are generally higher than those of the corresponding halo acids. Explain.

[10] Biomolecules
Chapter: [10] Biomolecules
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What are non-essential amino acids? Give two examples.

[10] Biomolecules
Chapter: [10] Biomolecules
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An organic compound with the molecular formula C9H10O forms 2, 4-DNP derivative, reduces Tollens’ reagent and undergoes Cannizzaro reaction. On vigorous oxidation, it gives 1, 2-benzenedicarboxylic acid. Identify the compound.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Describe the following:

Cannizzaro reaction

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

How will you bring about the following conversion?

Benzene to biphenyl

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

How the following conversion can be carried out?

Benzene to diphenyl

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Write the reactions involved in the following reactions: Clemmensen reduction

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Write the product(s) in the following reactions

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Write the product(s) in the following reactions

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

Give simple chemical tests to distinguish between the following pairs of compounds :

Propanol and 2-methylpropan-2-ol

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

Write the equation involved in the following reaction:

Etard reaction

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Write the formula of the compound of iodine which is obtained when conc. HNO3 oxidises I2

[7] P - Block Elements
Chapter: [7] P - Block Elements
Concept: undefined >> undefined
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