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Chemistry
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For a reaction: 

Rate = k

(i) Write the order and molecularity of this reaction.

(ii) Write the unit of k.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

For the first order thermal decomposition reaction, the following data were obtained:

Time / sec               Totalpressure / atm

0                              0.30

300                          0.50

Calculate the rate constant

(Given: log 2 = 0.301, log3 = 0.4771, log 4 = 0.6021)

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

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Write two factors that affect the rate of reaction.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

For a reaction A + B ⟶ P, the rate is given by

Rate = k [A] [B]2

How is the rate of reaction affected if the concentration of B is doubled?

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

For a reaction A + B ⟶ P, the rate is given by

Rate = k [A] [B]2

What is the overall order of reaction if A is present in large excess?

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

For a reaction : 

(i) Write the order and molecularity of this reaction.

(ii) Write the unit of k.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

For the hydrolysis of methyl acetate in aqueous solution, the following results were obtained :

t/s 0 30 60
[CH3COOCH3] / mol L–1 0.60 0.30 0.15

(i) Show that it follows pseudo first order reaction, as the concentration of water remains constant.

(ii) Calculate the average rate of reaction between the time interval 30 to 60 seconds.

(Given log 2 = 0.3010, log 4 = 0.6021)

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

Write the IUPAC name of the given compound:

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Write the names and structures of the monomers of the following polymers: Polyvinyl chloride

[15] Polymers
Chapter: [15] Polymers
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For a chemical reaction R → P, the variation in the concentration (R) vs. time (t) plot is given as:

(i) Predict the order of the reaction.

(ii) What is the slope of the curve?

(iii) Write the unit of rate constant for this reaction.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

Write the name of monomers used for getting the following polymers : Bakelite

[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined

The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume :

SO2Cl2 (g) → SO2 (g) + Cl2 (g)

Experiment Time/s–1 Total pressure/atm
1 0 0.4
2 100 0.7

Calculate the rate constant.

(Given : log 4 = 0.6021, log 2 = 0.3010)

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

Write the name of the monomer used for getting the following polymer:

Teflon

[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined

Solid A is a very hard electrical insulator in solid as well as in molten state and melts at extremely high temperature. What type of solid is it?

[1] Solid State
Chapter: [1] Solid State
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Ionic solids conduct electricity in molten state but not in solid state. Explain

[1] Solid State
Chapter: [1] Solid State
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What type of solids are electrical conductors, malleable and ductile?

[1] Solid State
Chapter: [1] Solid State
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Explain the basis of similarities between metallic and ionic crystals.

[1] Solid State
Chapter: [1] Solid State
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Explain ionic solids are hard and brittle.

[1] Solid State
Chapter: [1] Solid State
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Copper crystallises into a fcc lattice with edge length 3.61 × 10−8 cm. Show that the calculated density is in agreement with its measured value of 8.92 g cm−3.

[1] Solid State
Chapter: [1] Solid State
Concept: undefined >> undefined

Calculate the mass percentage of benzene (C6H6) and carbon tetrachloride (CCl4) if 22 g of benzene is dissolved in 122 g of carbon tetrachloride.

[1] Solutions
Chapter: [1] Solutions
Concept: undefined >> undefined
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