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Science (English Medium) इयत्ता १२ - CBSE Question Bank Solutions for Chemistry

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Chemistry
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Account for the following:

CH3CHO is more reactive than CH3COCH3 towards reaction with HCN.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Explain the following terms :

Half life period of a reaction (t1/2)

 

 
[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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 Following reaction takes place in the cell: 
`Zn(s) + Ag_2O(s)+H_2O(l) -> Zn^{2+}(aq) + 2Ag (s) + 2OH^- (aq)`
Calculate `Delta_r G^0` of the reaction

[Given ; `E^0_(Zn^{2+}//Zn)` = -0.76V

`E_((Zn^{2+}//Zn)) = 0.76V`

`E_(Ag^4//Ag)^0 = 0.80V, 1F = 96,500 C mol^-1 ]`
          

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Define the following terms with a suitable example of each: 
 Bactericidal antibiotics 

[16] Chemistry in Everyday Life
Chapter: [16] Chemistry in Everyday Life
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 Out of    and  , which one is optically active and why ?

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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Give one chemical test as an evidence to show that [Co (NH3)5Cl]  are ionisation isomers. 

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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The decomposition of a hydrocarbon has value of rate constant as 2.5×104s-1 At 27° what temperature would rate constant be 7.5×104 × 3 s-1if energy of activation is  19.147 × 103 J mol-1 ?

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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 Write a condition under which a bimolecular reaction is kinetically first order. Give an example of  such a reaction. (Given : log2 = 0.3010,log 3 = 0.4771, log5 = 0.6990).

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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 Predict the main product of the following reactions:

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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Why dextro and laevorotatory isomers of Butan-2-ol are difficult to separate by fractional distillation? 

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
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Write a chemical reaction to show that the open structure of D-glucose contains the following :  

Five alcohol groups

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Give reasons for the following:
The chemistry of actinoids elements is not so smooth as that of the lanthanoids.

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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Define the following term with a suitable example in each:
Broad-spectrum antibiotics

[16] Chemistry in Everyday Life
Chapter: [16] Chemistry in Everyday Life
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Define the following term with a suitable example in each:
Disinfectants

[16] Chemistry in Everyday Life
Chapter: [16] Chemistry in Everyday Life
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Why dextro and laevo rotatory isomers of Butan-2-ol are difficult to separate by fractional distillation?

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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At 100°C the vapour pressure of a solution containing 6.5 g a solute in 100 g water is 732 mm. If Kb = 0.52, the boiling point of this solution will be ______.

[1] Solutions
Chapter: [1] Solutions
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The coordination number of AB having rock salt geometry is ____________.

[1] Solid State
Chapter: [1] Solid State
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When a reversible work is done by a galvanic cell, the relationship between Gibbs free energy and emf of the cell is given by the relationship as ____________.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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The chemical reaction in which reactants require high amount of activation energy are generally ____________.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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The rate of chemical reaction becomes double for every 10° rise in temperature because of ____________.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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