Advertisements
Advertisements
प्रश्न
Show that in a cubic close packed structure, eight tetrahedral voids are present per unit cell.
Advertisements
उत्तर
In ccp structure unit cell is divided into 8 small cubes. Each small cube has atoms at alternative corners [Figure]. In all, each small cube has 4 atoms. When joined to one another, they make a regular tetrahedron. Thus, there is one tetrahedral void in each small cube and 8 tetrahedral void in total. Each of the eight small cubes has one void in one unit cell of ccp structure. We know that ccp structure has four atoms per unit cell. Thus the number of tetrahedral voids is twice the number of atoms.
(a)

(b)
Again, the number of tetrahedral voids in ccp structure is equal to twice the total number of atoms.
APPEARS IN
संबंधित प्रश्न
How will you distinguish between the following pair of terms?
Tetrahedral and octahedral voids
If the radius of the octahedral void is r and the radius of the atoms in close packing is R, derive the relation between r and R.
The unit cell of a substance has cations A+ at the corners of the unit cell and the anions B− at the center. The simplest formula of the substance is ____________.
Total number of voids in 0.5 mole of a compound which forms hexagonal close packed structure is ____________.
The Ca2+ and F– are located in CaF2 crystal, respectively at face centered cubic lattice points and in ____________.
If AgI crystallises in zinc blende structure with I– ions at lattice points. What fraction of tetrahedral voids is occupied by Ag+ ions?
Which set of following characteristics for ZnS crystal is correct?
In which of the following crystals alternate tetrahedral voids are occupied?
The number of octahedral voids present in a lattice is A. The number of closed packed articles, the number of tetrahedral voids generated is B the number of closed packed particles:
In the hexagonal close-packed structure of a metallic lattice, the number of nearest neighbours of a metallic atom is ____________.
In the cubic close packing, the unit cell has ______.
In which of the following arrangements octahedral voids are formed?
(i) hcp
(ii) bcc
(iii) simple cubic
(iv) fcc
The coordination number of Y will be in the XY types of crystal:
The number of tetrahedral voids per unit cell in NaCl crystal is:
(i) 4
(ii) 8
(iii) twice the number of octahedral voids.
(iv) four times the number of octahedral voids.
A solid compound XY has Nacl structure. If the radium of cation (X+) is 100 pm, the radium of anion (r–) will be:-
A compound is formed by two elements A and B. The element B forms a cubic close-packed structure and atoms of A occupy `1/3` of the tetrahedral voids. If the formula of the compound is AxBy then the value x + y is in the option:
