मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Show that in a cubic close packed structure, eight tetrahedral voids are present per unit cell.

Advertisements
Advertisements

प्रश्न

Show that in a cubic close packed structure, eight tetrahedral voids are present per unit cell.

दीर्घउत्तर
Advertisements

उत्तर

In ccp structure unit cell is divided into 8 small cubes. Each small cube has atoms at alternative corners [Figure]. In all, each small cube has 4 atoms. When joined to one another, they make a regular tetrahedron. Thus, there is one tetrahedral void in each small cube and 8 tetrahedral void in total. Each of the eight small cubes has one void in one unit cell of ccp structure. We know that ccp structure has four atoms per unit cell. Thus the number of tetrahedral voids is twice the number of atoms.

                  (a)


              (b)

Again, the number of tetrahedral voids in ccp structure is equal to twice the total number of atoms.

shaalaa.com
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 1: Solid States - Exercises [पृष्ठ १३]

APPEARS IN

एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 1 Solid States
Exercises | Q VI. 75. | पृष्ठ १३

संबंधित प्रश्‍न

What is the formula of a compound in which the element Y forms hcp lattice and atoms of X occupy 2/3rd of tetrahedral voids?


How will you distinguish between the following pair of terms?

Tetrahedral and octahedral voids


If the radius of the octahedral void is r and the radius of the atoms in close packing is R, derive the relation between r and R.


A compound is formed by two elements A and B. The element B forms cubic close packing and atoms of A occupy `1/3"rd"` of tetrahedral voids. The formula of this compound is ____________.


What is the coordination number of sodium in Na2O?


The Ca2+ and F– are located in CaF2 crystal, respectively at face centered cubic lattice points and in ____________.


Which set of following characteristics for ZnS crystal is correct?


The number of octahedral voids present in a lattice is A. The number of closed packed articles, the number of tetrahedral voids generated is B the number of closed packed particles:


In the cubic close packing, the unit cell has ______.


In which of the following arrangements octahedral voids are formed?

(i) hcp

(ii) bcc

(iii) simple cubic

(iv) fcc


Which of the following is not true about the voids formed in 3 dimensional hexagonal close packed structure?

(i) A tetrahedral void is formed when a sphere of the second layer is present above triangular void in the first layer.

(ii) All the triangular voids are not covered by the spheres of the second layer.

(iii) Tetrahedral voids are formed when the triangular voids in the second layer lie above the triangular voids in the first layer and the triangular shapes of these voids do not overlap.

(iv) Octahedral voids are formed when the triangular voids in the second layer exactly overlap with similar voids in the first layer.


In a compound, nitrogen atoms (N) make cubic close packed lattice and metal atoms (M) occupy one-third of the tetrahedral voids present. Determine the formula of the compound formed by M and N?


A solid compound XY has Nacl structure. If the radium of cation (X+) is 100 pm, the radium of anion (r–) will be:-


In which of the following structures coordination number for cations and anions in the packed structure will be same?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×