हिंदी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Show that in a cubic close packed structure, eight tetrahedral voids are present per unit cell.

Advertisements
Advertisements

प्रश्न

Show that in a cubic close packed structure, eight tetrahedral voids are present per unit cell.

दीर्घउत्तर
Advertisements

उत्तर

In ccp structure unit cell is divided into 8 small cubes. Each small cube has atoms at alternative corners [Figure]. In all, each small cube has 4 atoms. When joined to one another, they make a regular tetrahedron. Thus, there is one tetrahedral void in each small cube and 8 tetrahedral void in total. Each of the eight small cubes has one void in one unit cell of ccp structure. We know that ccp structure has four atoms per unit cell. Thus the number of tetrahedral voids is twice the number of atoms.

                  (a)


              (b)

Again, the number of tetrahedral voids in ccp structure is equal to twice the total number of atoms.

shaalaa.com
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 1: Solid States - Exercises [पृष्ठ १३]

APPEARS IN

एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 1 Solid States
Exercises | Q VI. 75. | पृष्ठ १३

संबंधित प्रश्न

How will you distinguish between the following pair of terms?

Tetrahedral and octahedral voids


If the radius of the octahedral void is r and the radius of the atoms in close packing is R, derive the relation between r and R.


How many tetrahedral voids can exist per unit cell in a hexagonal close packing sphere?


Total number of voids in 0.5 mole of a compound which forms hexagonal close packed structure is ____________.


A compound is formed by two elements A and B. The element B forms cubic close packing and atoms of A occupy `1/3"rd"` of tetrahedral voids. The formula of this compound is ____________.


What is the coordination number of sodium in Na2O?


In which of the following crystals alternate tetrahedral voids are occupied?


The number of octahedral voids present in a lattice is A. The number of closed packed articles, the number of tetrahedral voids generated is B the number of closed packed particles:


In the hexagonal close-packed structure of a metallic lattice, the number of nearest neighbours of a metallic atom is ____________.


If Germanium crystallises in the same way as diamond, then which of the following statement is not correct?


In the cubic close packing, the unit cell has ______.


In which of the following arrangements octahedral voids are formed?

(i) hcp

(ii) bcc

(iii) simple cubic

(iv) fcc


The coordination number of Y will be in the XY types of crystal:


The number of tetrahedral voids per unit cell in NaCl crystal is:

(i) 4

(ii) 8

(iii) twice the number of octahedral voids.

(iv) four times the number of octahedral voids.


In a compound, nitrogen atoms (N) make cubic close packed lattice and metal atoms (M) occupy one-third of the tetrahedral voids present. Determine the formula of the compound formed by M and N?


In which of the following structures coordination number for cations and anions in the packed structure will be same?


A compound is formed by two elements A and B. The element B forms a cubic close-packed structure and atoms of A occupy `1/3` of the tetrahedral voids. If the formula of the compound is AxBy then the value x + y is in the option:


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×