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A 5% solution of \[\ce{Na2SO4.10H2O}\] (MW = 3 22) is isotonic with 2% solution of non- electrolytic, non volatile substance X. Find out the molecular weight of X.
Concept: Expressing Concentration of Solutions
Write the two applications of Henry’s law.
Concept: Solubility >> Solubility of a Gas in a Liquid
Define “Molar conductivity”.
Concept: Conductance of Electrolytic Solutions >> Variation of Conductivity and Molar Conductivity with Concentration
How much electricity in terms of Faraday is required to produce 20 g of Ca from molten CaCl2?
(Given: Molar mass of Calcium is 40 g mol−1.)
Concept: Electrolytic Cells and Electrolysis
The conductivity of 0.20 M solution of KCl at 298 K is 0.025 S cm−1. Calculate its molar conductivity.
Concept: Conductance of Electrolytic Solutions >> Variation of Conductivity and Molar Conductivity with Concentration
State Kohlrausch Law.
Concept: Conductance of Electrolytic Solutions >> Variation of Conductivity and Molar Conductivity with Concentration
Using the E° values of A and B, predict which is better for coating the surface of iron [E°(Fe+2/Fe) = -0.44V] to prevent corrosion and why?
Given: E° (A+2/A)=-2.37 V: E°(B+2/B)= -0.14V
Concept: Electrolytic Cells and Electrolysis
The conductivity of 0.001 mol L-1 solution of CH3COOH is 3.905× 10-5 S cm-1. Calculate its molar conductivity and degree of dissociation (α) Given λ°(H+)= 349.6 S cm2 mol-1 and λ°(CH3COO)= 40.9S cm2mol-1.
Concept: Conductance of Electrolytic Solutions >> Variation of Conductivity and Molar Conductivity with Concentration
Define electrochemical cell
Concept: Batteries >> Primary Batteries
Following reactions occur at cathode during the electrolysis of aqueous sodium chloride solution:
Na+(aq) + e− ⟶ Na (s) E0 = 2.71 V
H+(aq) + e− ⟶ `1/2` H2 (g) E0 = 0.00 V
On the basis of their standard reduction electrode potential (E0) values, which reaction is feasible at the cathode and why?
Concept: Electrolytic Cells and Electrolysis
Why does the cell potential of mercury cell remain constant throughout its life?
Concept: Batteries >> Primary Batteries
Define the following terms: Molar conductivity (⋀m)
Concept: Conductance of Electrolytic Solutions >> Variation of Conductivity and Molar Conductivity with Concentration
Define the following terms: Secondary batteries
Concept: Batteries >> Primary Batteries
Calculate the standard cell potential of a galvanic cell in which the following reaction takes place:
\[\ce{2Cr_{(s)} + 3Cd{^{2+}_{(aq)}} -> 2Cr{^{3+}_{(aq)}} + 3Cd_{(s)}}\]
Calculate the ΔrG° and equilibrium constant of the reaction.
Concept: Galvanic Cells - Measurement of Electrode Potential
Define conductivity for the solution of an electrolyte.
Concept: Conductance of Electrolytic Solutions >> Measurement of the Conductivity of Ionic Solutions
Write the name of the cell which is generally used in transistors. Write the reactions taking place at the anode and the cathode of this cell.
Concept: Electrolytic Cells and Electrolysis
The cell in which the following reaction occurs:
`2Fe^(3+) (aq) + 2I^(-) (aq) ---> 2Fe^(2+) (aq) + I_2 (s)` has `E_"cell"^@` = 0.236 V at 298 K. Calculate the standard Gibbs energy of the cell reaction. (Given : 1 F = 96,500 C mol−1)
Concept: Nernst Equation >> Electrochemical Cell and Gibbs Energy of the Reaction
How many electrons flow through a metllic wire if a current of 0·5 A is passed for 2 hours? (Given : 1 F = 96,500 C mol−1)
Concept: Electrochemical Cells
Following reactions occur at cathode during the electrolysis of aqueous copper(II) chloride solution :

On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why ?
Concept: Electrolytic Cells and Electrolysis
Although chlorine is an electron withdrawing group, yet it is ortho-, para- directing in electrophilic aromatic substitution reactions. Why?
Concept: Concept of Electrochemistry
