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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Write chemical reactions to convert phenol into salicyaldehyde. Write the name of the reaction. What happens when if CCl4 is used instead of CHCl3 in the above reaction.

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प्रश्न

Write chemical reactions to convert phenol into salicyaldehyde. Write the name of the reaction. What happens when if CCl4 is used instead of CHCl3 in the above reaction.

दीर्घउत्तर
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उत्तर

  1. Phenol to salicyaldehyde: When phenol is treated with chloroform in an aqueous sodium hydroxide solution followed by hydrolysis with acid, salicylaldehyde is formed.
  2. This reaction is known as the Reimer-Tiemann reaction.
  3. If the solvent chloroform (CHCl3) is replaced by carbon tetrachloride (CCl4), salicylic acid is formed.
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पाठ 11: Alcohols, Phenols and Ethers - Long Answer Questions

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