Advertisements
Advertisements
प्रश्न
Write chemical reactions to convert phenol into salicyaldehyde. Write the name of the reaction. What happens when if CCl4 is used instead of CHCl3 in the above reaction.
Advertisements
उत्तर
- Phenol to salicyaldehyde: When phenol is treated with chloroform in an aqueous sodium hydroxide solution followed by hydrolysis with acid, salicylaldehyde is formed.

- This reaction is known as the Reimer-Tiemann reaction.
- If the solvent chloroform (CHCl3) is replaced by carbon tetrachloride (CCl4), salicylic acid is formed.
APPEARS IN
संबंधित प्रश्न
Choose the correct option.
Which is the most resistant alcohol towards oxidation reaction among the following?
Reaction between hot conc. HI and anisole gives ______________
What is the action of following reagents on pent-3-enal?
- H2/Ni
- LiAlH4/H3O+
Write Kolbe’s reaction.
Name the reagents used to convert phenol into
- picric acid
- p-benzoquinone
Write chemical equation of acetyl chloride with phenol
An unknown alcohol is treated with Lucas reagent. Explain how you will determine whether the alcohol is primary, secondary or tertiary. Indicate by chemical equation the reaction between isopropyl alcohol and Lucas reagent.
How will you bring about the following conversions?
2-methyl propan-2-ol to 2-methylpropene
\[\ce{C3H8O ->[KMnO4][(Oxidation)] C3H6O2}\]
The compound C3H8O is a/an ____________.
Propane when treated with cold cone. H2SO4 forms a compound which on heating with water gives ______.
Carbolic acid is oxidised by acidified sodium dichromate to give ______.
In Dow process, chlorobenzene is converted into phenol by ____________.
____________ will NOT undergo acetylation.
Sodium benzene sulphonate reacts with NaOH and then on acidic hydrolysis, it gives __________.
In Raschig's method for synthesis of phenol, the reactants used are ____________.
The number of moles of hydrogen gas formed when 2 moles of 2-methylpropan-2-ol reacts with aluminium is ____________.
What is INCORRECT about the product written in the below given reaction?
\[\ce{R - CH2 - OH ->[PCC] R - COOH}\]
Which among the following is allylic secondary alcohol?
Identify 'Z' in the following series of reaction:
\[\ce{Butan - 2 - ol ->[PCl3] X ->[alco. KOH] Y ->[i) H2SO4][ii) H-OH/heat] Z}\]
Identify the alcohol that reacts immediately with Lucas reagent?
Which of the following compounds reacts immediately with Lucas reagent?
What is the product obtained in Reimer - Tiemann reaction?
The chemical test that distinguish between benzoic acid and phenol is ______.
Arrange O - H, C - H and N - H bonds in increasing order of their bond polarity.
Write the product when 1°, 2° and 3° alcohol vapours are passed over hot copper.
Write the chemical reaction when hot copper is treated with Vapours of 2° (secondary) alcohol.
Explain: Phenols are acid while alcohol is neutral.
What is the commercial method of preparation of phenol?
