मराठी

Write Chemical Equation in Support of Your Answer. Out of Cl and Ch2- Cl, Which One is More Reactive Towards Nucleophilic Substitution Reaction and Why?

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प्रश्न

Write chemical equation in support of your answer. 
 Out of   Cl and  CH2- Cl,  which one is more reactive towards nucleophilic substitution reaction and why? 

टीपा लिहा
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उत्तर

  CH2 - Cl , will be more reactive towards  SN2  reaction as in case of  reaction as in case of Cl the back side attack will be very difficult.

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2018-2019 (March) 56/3/2

व्हिडिओ ट्यूटोरियलVIEW ALL [1]

संबंधित प्रश्‍न

What happens when \[\ce{CH3 - Br}\] is treated with KCN?


The presence of nitro group (−NO2) at o/p positions increases the reactivity of haloarenes towards nucleophilic substitution reactions.


Give reasons:

The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride.


Assertion: Presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution.

Reason: Nitro group, being an electron-withdrawing group decreases the electron density over the benzene ring.


Which of the following compounds will give racemic mixture on nucleophilic substitution by \[\ce{OH-}\] ion?

(a) \[\begin{array}{cc}
\phantom{}\ce{CH3 - CH - Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]

 

(b) \[\begin{array}{cc}
\phantom{..}\ce{Br}\\
\phantom{}|\\
\phantom{}\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]

 

(c) \[\begin{array}{cc}
\phantom{....}\ce{CH3 - CH - CH2Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]


Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

Haloarenes are less reactive than haloalkanes and haloalkenes. Explain.


Why haloarenes are not reactive towards nucleophilic substitution reaction? Give two reactions.


Identify the final product [D] obtained in the following sequence of reactions.

\[\ce{CH3CHO \underset{ii) H2O+}{\overset{i) LiAlH4}{->}} [A] \underset{\triangle}{\overset{H2SO4}{->}} [B]}\]


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