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प्रश्न
What is meant by the term ‘coordination number’?
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उत्तर
The number of nearest neighbours with which a given particle is in direct contact in a crystal is called the coordination number.
संबंधित प्रश्न
What is the formula of a compound in which the element Y forms ccp lattice and atoms of X occupy 1/3rd of tetrahedral voids?
Define the following term: Primitive unit cells
An ionic crystal lattice has limiting value of radius ratio as 0.414 to 0.732; the co-ordination number of its cation is _______.
(A) 6
(B) 4
(C) 3
(D) 12
Which of the following parameters are correct for triclinic lattice?
(A) α = β = γ = 90° and a = b = c
(B) α ≠ β ≠ γ = 90° and a ≠ b ≠ c
(C) α = γ = 90°, β ≠ 90° and a ≠ b ≠ c
(D) α ≠ β ≠ γ ≠ 90° and a ≠ b ≠ c
Calculate the number of atoms present in 2 gram of crystal which has face-centred cubic
(FCC) crystal lattice having edge length of 100 pm and density 10 gcm−3
An ionic crystal lattice has `r^+/r` radius ratio of 0.320, its coordination number is __
(a) 3
(b) 4
(c) 6
(d) 8
In the complexes `[Fe(CN)_6]^(3-)` and `[pt(en) (H_2O)_2(NO_2 (Cl)^(2+)]``the respective oxidation numbers of central metal atoms are
1) +3 and +4
2) +6 and + 4
3) +6 and +3
4) +3 and + 3
For a crystal of sodium chloride, state the type of lattice in which it crystallises.
i)
Consider the following cell reaction at 298 K: [3]
2Ag+ + Cd → 2Ag + Cd2+
The standard reduction potentials (E°) for Ag+/Ag and Cd2-/Cd are 0.80 V and -0.40 V respectively:
(1) Write the cell representation.
(2) What will be the emf of the cell if the concentration of Cd2+ is 0.1M and that of Ag+ is 0.2 M?
(3) Will the cell work spontaneously for the condition given in (2) above?
(ii)
What is a buffer solution? How is it prepared? Explain the buffer action of a basic buffer with a suitable example.
How will you obtain pure potassium permanganate (KMnO4) crystals from its ore, pyrolusite? Give the steps involved and the reactions.
In a crystal of diamond:
- How many carbon atoms are present per unit cell?
- What type of lattice does diamond crystallise in?
- How many carbon atoms surround each carbon atom?
- How are they arranged?
In a solid atom M occupies ccp lattice and `(1/3)` of tetrahedral voids are occupied by atom N. find the formula of solid formed by M and N.
Crystals can be classified into basic crystal units, equal to ____________.
The lattice site in a pure crystal cannot be occupied by ______.
AB crystallises in a body centred cubic lattice with edge length' a' equal to 387 pm The distance between two oppositely charged ions in the lattice is:
A particular solid is very hard and has a high melting point. In solid state, it is a non-conductor and in molten state, it is a conductor of electricity. Classify the solid ______.
How many unit cells are present in a cube-shaped ideal crystal of NaCl of mass 1.00 g? [Atomic masses: Na = 23, Cl = 35.5]
