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प्रश्न
Van’t Hoff factor i is given by the expression:
(i) i = `"Normal molar mass"/"Abnormal molar mass"`
(ii) i = `"Abnormal molar mass"/"Normal molar mass"`
(iii) i = `"Observed colligative property"/"Calculated colligative property"`
(iv) i = `"Calculated colligative property"/"Observed colligative property"`
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उत्तर
(i) i = `"Normal molar mass"/"Abnormal molar mass"`
(iii) i = `"Observed colligative property"/"Calculated colligative property"`
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संबंधित प्रश्न
Define van’t Hoff factor.
3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62 K. Calculate the van't Hoff factor and predict the nature of solute (associated or dissociated).
(Given : Molar mass of benzoic acid = 122 g mol−1, Kf for benzene = 4.9 K kg mol−1)
Define the term Abnormal molar mass
How van’t Hoff factor is related to the degree of dissociation?
How will you convert the following in not more than two steps:
Benzoic acid to Benzaldehyde
How will you convert the following in not more than two steps:
Acetophenone to Benzoic acid
Give reasons for the following
Elevation of the boiling point of 1 M KCl solution is nearly double than that of 1 M sugar solution.
The Van't Hoff factor (i) for a dilute aqueous solution of the strong elecrolyte barium hydroxide is (NEET) ______.
We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentrations 0.1 M, 0.01 M and 0.001 M, respectively. The value of van’t Hoff factor for these solutions will be in the order ______.
Van't Hoff factor I is given by expression.
When 9.45 g of ClCH2COOH is added to 500 mL of water, its freezing point drops by 0.5°C. The dissociation constant of ClCH2COOH is x × 10−3. The value of x is ______. (Rounded-off to the nearest integer)
[\[\ce{K_{f(H_2O)}}\] = 1.86 K kg mol−1]
A storage battery contains a solution of H2SO4 38% by weight. At this concentration, Van't Hoff Factor is 2.50. At the battery content freeze temperature will be ______ K.
(Kf = 1.86 K Kg mol−1)
The degree of dissociation of Ca(NO3)2 in a dilute aqueous solution containing 7 g of the salt per 100 g of water at 100°C is 70%. If the vapour pressure of water at 100°C is 760 mm. The vapour pressure of the solution is ______ mm.
Consider the reaction
\[\begin{bmatrix}\begin{array}{cc}
\phantom{.......}\ce{CH3}\\
\phantom{....}|\\
\ce{CH3CH2CH2 - \overset{⊕}{N} - CH2CH3}\\
\phantom{....}|\\
\phantom{.......}\ce{CH3}
\end{array}\end{bmatrix}\]\[\ce{OH^- ->[Heat] ?}\]
Which of the following is formed in a major amount?
A molecule M associates in a given solvent according to the equation \[\ce{M <=> (M)_n}\]. For a certain concentration of M, the van't Hoff factor was found to be 0.9 and the fraction of associated molecules was 0.2. The value of n is ______.
When 19.5 g of F – CH2 – COOH (Molar mass = 78 g mol−1), is dissolved in 500 g of water, the depression in freezing point is observed to be 1°C. Calculate the degree of dissociation of F – CH2 – COOH.
[Given: Kf for water = 1.86 K kg mol−1]
