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प्रश्न
Van’t Hoff factor i is given by the expression:
(i) i = `"Normal molar mass"/"Abnormal molar mass"`
(ii) i = `"Abnormal molar mass"/"Normal molar mass"`
(iii) i = `"Observed colligative property"/"Calculated colligative property"`
(iv) i = `"Calculated colligative property"/"Observed colligative property"`
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उत्तर
(i) i = `"Normal molar mass"/"Abnormal molar mass"`
(iii) i = `"Observed colligative property"/"Calculated colligative property"`
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संबंधित प्रश्न
Derive van’t Hoff general solution equation.
The substance ‘X’, when dissolved in solvent water gave molar mass corresponding to the molecular formula ‘X3’. The van’t Hoff factor (i) is _______.
(A) 3
(B) 0.33
(C) 1.3
(D) 1
19.5 g of CH2FCOOH is dissolved in 500 g of water. The depression in the freezing point of water observed is 1.0°C. Calculate the van’t Hoff factor and dissociation constant of fluoroacetic acid.
How will you convert the following in not more than two steps:
Benzoic acid to Benzaldehyde
How will you convert the following in not more than two steps:
Acetophenone to Benzoic acid
Give reasons for the following
Elevation of the boiling point of 1 M KCl solution is nearly double than that of 1 M sugar solution.
Predict whether van’t Hoff factor, (i) is less than one or greater than one in the following:
CH3COOH dissolved in water
The Van't Hoff factor (i) for a dilute aqueous solution of the strong elecrolyte barium hydroxide is (NEET) ______.
The freezing point depression constant for water is 1.86° K Kg mol-1. If 5 g Na2SO4 is dissolved in 45 g water, the depression in freezing point is 3.64°C. The Vant Hoff factor for Na2SO4 is ______.
Phenol dimerizes in benzene having van’t Hoff factor 0.54. What is the degree of association?
The values of Van’t Hoff factors for KCl, NaCl and K2SO4, respectively, are ______.
Van't Hoff factor I is given by expression.
Geraniol, a volatile organic compound, is a component of rose oil. The density of the vapour is 0.46 g L–1 at 257°C and 100 mm Hg. The molar mass of geraniol is ______ g mol–1. (Nearest Integer)
[Given: R = 0.082 L atm K–1 mol–1]
When 9.45 g of ClCH2COOH is added to 500 mL of water, its freezing point drops by 0.5°C. The dissociation constant of ClCH2COOH is x × 10−3. The value of x is ______. (Rounded-off to the nearest integer)
[\[\ce{K_{f(H_2O)}}\] = 1.86 K kg mol−1]
Consider the reaction
\[\begin{bmatrix}\begin{array}{cc}
\phantom{.......}\ce{CH3}\\
\phantom{....}|\\
\ce{CH3CH2CH2 - \overset{⊕}{N} - CH2CH3}\\
\phantom{....}|\\
\phantom{.......}\ce{CH3}
\end{array}\end{bmatrix}\]\[\ce{OH^- ->[Heat] ?}\]
Which of the following is formed in a major amount?
A molecule M associates in a given solvent according to the equation \[\ce{M <=> (M)_n}\]. For a certain concentration of M, the van't Hoff factor was found to be 0.9 and the fraction of associated molecules was 0.2. The value of n is ______.
When 19.5 g of F – CH2 – COOH (Molar mass = 78 g mol−1), is dissolved in 500 g of water, the depression in freezing point is observed to be 1°C. Calculate the degree of dissociation of F – CH2 – COOH.
[Given: Kf for water = 1.86 K kg mol−1]
