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The standard enthalpy of formation of water is - 286 kJ mol-1. Calculate the enthalpy change for the formation of 0.018 kg of water. - Chemistry

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प्रश्न

The standard enthalpy of formation of water is - 286 kJ mol-1. Calculate the enthalpy change for the formation of 0.018 kg of water.

संख्यात्मक
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उत्तर

Mass of H2O = 0.018 kg = 18 g

Number of moles of H2O = `("Mass of H"_2"O")/("Molar mass of H"_2"O") = (18  "g")/(18  "g mol"^-1)` = 1 mol

The thermochemical equation is,

\[\ce{H_{2(g)} + \frac{1}{2} O_{2(g)} -> H2O_{(l)}}\], ΔfH° = – 286 kJ mol–1

∴ Enthalpy change for formation of 1 mole H2O = - 286 kJ

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पाठ 4: Chemical Thermodynamics - Very short answer questions

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एससीईआरटी महाराष्ट्र Chemistry [English] 12 Standard HSC
पाठ 4 Chemical Thermodynamics
Very short answer questions | Q 3

संबंधित प्रश्‍न

Answer in brief.

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a) to melt 180 g of ice at 0 °C

b) heat it to 100 °C and then

c) vapourise it at that temperature.

[Given: ΔfusH° (ice) = 6.01 kJ mol-1 at 0 °C, ΔvapH° (H2O) = 40.7 kJ mol-1 at 100 °C, Specific heat of water is 4.18 J g-1 K-1]


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\[\ce{2Fe_{(s)} + \frac{3}{2} O_{2(g)} -> Fe2O_{3(s)}}\]

Given:

1. \[\ce{2Al_{(s)} + Fe2O_{3(s)} -> 2Fe_{(s)} + Al_2O_{3(s)}}\], rH° = –847.6 kJ
2. \[\ce{2Al_{(s)} + \frac{3}{2} O_{2(g)} -> Al2O_{3(s)}}\], rH° = –1670 kJ

Write an application of Hess’s law.


When 2 moles of C2H6(g) are completely burnt, 3129 kJ of heat is liberated. If ∆Hf for CO2(g) and H2O(l) are −395 and −286 kJ per mole respectively, the heat combustion of C2H6(g) is ____________.


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\[\ce{CH2O_{(g)} + O2_{(g)} -> CO2_{(g)} + H2O_{(g)}}\] ΔH = −527 kJ

How much heat will be evolved in the formation of 60 g of CO2?


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Calculate the standard enthalpy of formation of CH3OH(l) from the following data:

  1. \[\ce{CH3OH_{(l)} + 3/2 O2_{(g)} -> CO2_{(g)} + 2H2O_{(l)}ΔH^° = - 726 kJ mol^{-1}}\]
  2. \[\ce{C_{(s)} + O2_{(g)} → CO2_{(g)}Δ_cH^° = – 393 kJ mol^{-1}}\]
  3. \[\ce{H2_{(g)} + 1/2 O2_{(g)} -> H2O_{(l)}Δ_fH^° = - 286 kJ mol^{-1}}\]

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Define and explain the term, enthalpy of reaction.


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ΔcH0[CH3CHO(l)] = - 1166 kJ mol-1


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Draw energy profile diagram and show:

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  2. energy of activation for forward and backward reactions
  3. enthalpy of reaction

Calculate ΔsubH of the H2O from the given data:
\[\ce{H2O_{(s)}->H2O_{(l)},}\] ΔfusH = 6.01kJ mol−1

\[\ce{H2O_{(l)}-> H2O_{(g)},}\] ΔVapH = 45.07 kJ mol−1.


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Given: \[\ce{C2H2_{(g)} + 5/2O_{2(g)}-> 2CO_{2(g)} + H2O_{(l)} \Delta_{(c)}H^{0} = - 1300 kJ}\]


Calculate the standard enthalpy of combustion of methane if the standard enthalpy of formation of methane, carbon dioxide and water are −74.8, −393.5 and −285.8 kJmol−1 respectively.


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