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The standard enthalpy of formation of water is - 286 kJ mol-1. Calculate the enthalpy change for the formation of 0.018 kg of water. - Chemistry

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प्रश्न

The standard enthalpy of formation of water is - 286 kJ mol-1. Calculate the enthalpy change for the formation of 0.018 kg of water.

संख्यात्मक
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उत्तर

Mass of H2O = 0.018 kg = 18 g

Number of moles of H2O = `("Mass of H"_2"O")/("Molar mass of H"_2"O") = (18  "g")/(18  "g mol"^-1)` = 1 mol

The thermochemical equation is,

\[\ce{H_{2(g)} + \frac{1}{2} O_{2(g)} -> H2O_{(l)}}\], ΔfH° = – 286 kJ mol–1

∴ Enthalpy change for formation of 1 mole H2O = - 286 kJ

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पाठ 4: Chemical Thermodynamics - Very short answer questions

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एससीईआरटी महाराष्ट्र Chemistry [English] 12 Standard HSC
पाठ 4 Chemical Thermodynamics
Very short answer questions | Q 3

संबंधित प्रश्‍न

Answer in brief.

What is the standard enthalpy of combustion? Give an example.


Calculate enthalpy of formation of HCl if bond enthalpies of H2, Cl2 and HCl are 434 kJ mol-1, 242 kJ mol–1 and 431 kJ mol–1 respectively.


State and explain Hess’s law of constant heat summation.


Calculate the standard enthalpy of formation of liquid methanol from the following data:

  1. \[\ce{CH3OH_{(l)} + \frac{3}{2} O_{2(g)} -> CO_{2(g)} + 2H2O_{(l)}}\]     ∆H° = – 726 kJ mol–1
  2. \[\ce{C_{(Graphite)} + O_{2(g)} -> CO_{2(g)}}\]          ∆cH° = – 393 kJ mol–1
  3. \[\ce{H_{2(g)} + \frac{1}{2} O_{2(g)} -> H2O_{(l)}}\]          ∆fH° = – 286 kJ mol–1 

Define the Bond enthalpy.


Calculate the standard enthalpy of the reaction.

\[\ce{2Fe_{(s)} + \frac{3}{2} O_{2(g)} -> Fe2O_{3(s)}}\]

Given:

1. \[\ce{2Al_{(s)} + Fe2O_{3(s)} -> 2Fe_{(s)} + Al_2O_{3(s)}}\], rH° = –847.6 kJ
2. \[\ce{2Al_{(s)} + \frac{3}{2} O_{2(g)} -> Al2O_{3(s)}}\], rH° = –1670 kJ

Write an application of Hess’s law.


A compound that has a high negative heat of formation is normally ____________.


The heat of formations of CO(g) and CO2(g) are −26.4 kcal and −94.0 kcal respectively. The heat of combustion of carbon monoxide will be ____________.


The standard heats of formation for CCl4(g), H2O(g), CO2(g), and HCl(g) are −25.5, −57.8, −94.1 and −22.1 kcal mol−1, respectively.

∆H for the reaction

\[\ce{CCl4_{(g)} + 2H2O_{(g)} -> CO2_{(g)} + 4HCl_{(g)}}\] at 298 K


The standard heats of formation in kcal mol−1 of NO2(g) and N2O4(g) are 8.0 and 2.0 respectively. The heat of dimerization of NO2 in kcal is ____________.

\[\ce{2NO2_{(g)} ⇌ N2O4_{(g)}}\]


The enthalpy change accompanying a reaction in which 1 mole of the substance in the standard state reacts completely with oxygen or is completely burnt is called as ____________.


lf, \[\ce{C_{(s)} + O2_{(g)} -> CO2_{(g)}}\], ∆H = x .........(i)

\[\ce{CO_{(g)} + 1/2O2_{(g)} -> CO2_{(g)}}\], ∆H = y .......(ii)

Then, the heat of formation of CO is:


Which among the following salts, solubility decreases with increase in temperature?


The heat evolved in the combustion of benzene is given by

\[\ce{C6H6 + 7 1/2O2 -> 6CO2_{(g)} + 3H2O_{(l)}}\]; ΔH = −3264.6 kJ

Which of the following quantities of heat energy will be evolved when 39 g C6H6 are burnt?


Calculate the enthalpy of hydrogenation of C2H4(g), given that the enthalpy of formation of ethane and ethylene are −30.2 kcal and +12.5 kcal respectively.


Combustion of glucose takes place as

\[\ce{C6H12O6_{(s)} + 6O2_{(g)} -> 6CO2_{(g)} + 6H2O_{(g)}}\]; ΔH = −72 kcal mol−1

The energy needed for the production of 1.8 g of glucose by photosynthesis will be ___________.


Heat of formation of water is - 272 kJ mol-1. What quantity of water is converted to H2 and O2 by 750 kJ of heat?


Standard entropies of N2(g), H2(g), and NH3(g) are a1, a2 and a3 J K-1 mol-1 respectively. What is value of ΔS° for formation of NH3(g)?


From the following bond energies:

H – H bond energy: 431.37 kJ mol−1

C = C bond energy: 606.10 kJ mol−1

C – C bond energy: 336.49 kJ mol−1

C – H bond energy: 410.50 kJ mol−1

Enthalpy for the given reaction will be:

\[\begin{array}{cc}
\phantom{}\ce{H}\phantom{...}\ce{H}\phantom{...................}\ce{H}\phantom{...}\ce{H}\phantom{....}\\
\phantom{.}|\phantom{....}|\phantom{....................}|\phantom{....}|\phantom{.....}\\
\ce{C = C + H - H -> H - C - C - H}\\
\phantom{.}|\phantom{....}|\phantom{....................}|\phantom{....}|\phantom{.....}\\
\phantom{}\ce{H}\phantom{...}\ce{H}\phantom{...................}\ce{H}\phantom{...}\ce{H}\phantom{....}
\end{array}\]


What is enthalpy of formation of NH3 if bond enthalpies as (N ≡ N) = - 941 kJ/mol.

\[\ce{(H - H)}\] = 436 kJ/mol and \[\ce{(N - H)}\] = 389 kJ/mol?


Define and explain the term, enthalpy of reaction.


Calculate the standard enthalpy of the reaction, \[\ce{SiO2_{(s)} + 3C_{(graphite)} -> SiC_{(s)} + 2CO_{(g)}}\] from the following reactions:

  1. \[\ce{Si_{(s)} + O2_{(g)} -> SiO2_{(s)}}\], ΔrH0 = −911 kJ
  2. \[\ce{2C_{(graphite)} + O2_{(g)} -> 2CO_{(g)}}\], ΔrH= −221 kJ
  3. \[\ce{Si_{(s)} + C_{(graphite)} -> SiC_{(s)}}\], ΔrH= −65.3 kJ

Which of the following reactions defines the enthalpy of formation?


Standard enthalpy of combustion of a substance is given. Then Write thermochemical equation.

ΔcH0[C2H5OH(1)] = - 1409 kJ mol-1


Standard enthalpy of combustion of a substance is given. Then Write thermochemical equation.

ΔcH0[CH3CHO(l)] = - 1166 kJ mol-1


Heat of combustion of methane is - 890 kJ/mol. On combustion of 12 gm of methane in excess of oxygen, ______ heat is evolved.


Calculate ΔsubH of the H2O from the given data:
\[\ce{H2O_{(s)}->H2O_{(l)},}\] ΔfusH = 6.01kJ mol−1

\[\ce{H2O_{(l)}-> H2O_{(g)},}\] ΔVapH = 45.07 kJ mol−1.


Calculate the standard enthalpy of combustion of methane if the standard enthalpy of formation of methane, carbon dioxide and water are −74.8, −393.5 and −285.8 kJmol−1 respectively.


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