Advertisements
Advertisements
प्रश्न
Write the mathematical relation between ΔH and ΔU during the formation of one mole of CO2 under standard conditions.
Advertisements
उत्तर
Formation of one mole of CO2 under standard conditions:
\[\ce{C_{(s)} + O_{2(g)} -> CO_{2(g)}}\]
Δng = (moles of product gases) − (moles of reactant gases)
Δng = 1 – 1 = 0
Now, ΔH = ΔU + ∆ngRT
ΔH = ΔU + 0 × RT
∴ ΔH = ΔU
APPEARS IN
संबंधित प्रश्न
Answer in brief.
Obtain the expression for work done in chemical reaction.
Obtain the relationship between ΔH and ΔU for gas phase reactions.
Calculate the work done in the decomposition of 132 g of \[\ce{NH4NO3}\] at 100°C.
\[\ce{NH4NO3_{(s)} -> N2O_{(g)} + 2H2O_{(g)}}\]
State whether work is done on or by the system.
Answer the following question.
Calculate standard enthalpy of reaction,
Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g), from the following data.
Δf H°(Fe2O3) = - 824 kJ/mol,
Δf H°(CO) = - 110 kJ/mol,
Δf H°(CO2) = - 393 kJ/mol
Calculate the work done and comment on whether work is done on or by the system for the decomposition of 2 moles of NH4NO3 at 100 °C
NH4NO3(s) → N2O(g) + 2H2O(g)
Write the expression showing the relation between enthalpy change and internal energy change for gaseous phase reaction.
An ideal gas expands from the volume of 1 × 10–3 m3 to 1 × 10–2 m3 at 300 K against a constant pressure at 1 × 105 Nm–2. The work done is
Define enthalpy of combustion.
Define enthalpy of neutralization.
For which of the following ∆U = ∆H?
The difference between heats of reaction at constant pressure and at constanl volume for the reaction
\[\ce{2C6H6_{(l)} + 15O2_{(g)} -> 12CO2_{(g)} + 6H2O_{(l)}}\] at 25°C in kJ
When 6.0 g of O2 reacts with CIF as per \[\ce{2ClF_{(g)} + O2_{(g)} -> Cl2O_{(g)} + OF2_{(g)}}\] the enthalpy change is 38.55 kJ. The standard enthalpy of the reaction is ____________.
The enthalpy change for two reactions are given by the equations
\[\ce{2Cr_{(s)} + 1.5 O2_{(g)} -> Cr2O3_{(s)}}\];
∆H1 = −1130 kJ ............(i)
\[\ce{C_{(s)} + 0.5 O2_{(g)} -> CO_{(g)}}\];
∆H2 = −110 kJ .........(ii)
What is the enthalpy change, in kJ, for the following reaction?
\[\ce{3C_{(s)} + Cr2O3_{(s)} -> 2Cr_{(s)} + 3CO_{(g)}}\]
Given the bond energies N ≡ N, H – H and N – H bonds are 945, 436 and 391 kJ/mol respectively. The enthalpy of the reaction;
\[\ce{N2_{(g)} + 3H2_{(g)} -> 2NH3_{(g)}}\]
In which of the following reactions does the heat change represent the heat of formation of water?
Work done when 2 moles of an ideal gas is compressed from a volume of 5 m3 to 1 dm3 at 300 K, under a pressure of 100 kPa is ____________.
For the reaction, \[\ce{N_{2(g)} + 3H_{2(g)} -> 2NH_{3(g)}}\], ΔH is equal to ______.
What is the amount of work done when 0.5 mole of methane, CH4 (g), is subjected to combustion at 300 K? (Given, R = 8.314 JK-1mol-1)
Calculate ΔU if 2 kJ heat is released and 10 kJ of work is done on the system.
Calculate the work done during the combustion of 0.138 kg of ethanol, C2H5OH(l) at 300 K.
Given: R = 8.314 Jk−1 mol−1, molar mass of ethanol = 46 g mol−1.
Calculate ΔS of the surrounding if the standard enthalpy of formation of methanol is − 238.9 kJ mol−1.
Calculate the standard entropy change of the surrounding if standard enthalpy of formation of methyl alcohol is –240 kJ mol-1.
The equilibrium concentrations of the species in the reaction \[ \mathrm{A} + \mathrm{B} \rightleftharpoons \mathrm{C} + \mathrm{D} \] are 2, 3, 10 and 6 mol L-1, respectively at 300 K. ΔGº for the reaction is (R = 2 cal/mol K)
