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Propanal and Pentan-3-one Are the Ozonolysis Products of an Alkene? What is the Structural Formula of the Alkene?

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प्रश्न

Propanal and pentan-3-one are the ozonolysis products of an alkene? What is the structural formula of the alkene?

थोडक्यात उत्तर
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उत्तर

As per the given information, propanal and pentan-3-one are the ozonolysis products of an alkene. Let the given alkene be ‘A’. Writing the reverse of the ozonolysis reaction, we get:

The products are obtained on the cleavage of ozonide ‘X’. Hence, ‘X’ contains both products in the cyclic form. The possible structure of ozonide can be represented as:

Now, ‘X’ is an addition product of alkene ‘A’ with ozone. Therefore, the possible structure of alkene ‘A’ is:

\[\begin{array}{cc}
\ce{H3C - CH2 - CH = C - CH2 - CH3}\\
\phantom{.......}|\\
\phantom{..............}\ce{CH2CH3}
\end{array}\]

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पाठ 13: Hydrocarbons - EXERCISES [पृष्ठ ४०५]

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एनसीईआरटी Chemistry - Part 1 and 2 [English] Class 11
पाठ 13 Hydrocarbons
EXERCISES | Q 13.7 | पृष्ठ ४०५

संबंधित प्रश्‍न

An alkene ‘A’ on ozonolysis gives a mixture of ethanal and pentan-3-one. Write structure and IUPAC name of ‘A’.


An alkene ‘A’ contains three C – C, eight C – H σ bonds and one C – C π bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write IUPAC name of ‘A’.


Write a chemical equation for combustion reaction of the following hydrocarbon:

Butane


Write a chemical equation for combustion reaction of the following hydrocarbon: 

Pentene 


Write a chemical equation for combustion reaction of the following hydrocarbon:

Hexyne


The addition of HBr to 1-butene gives a mixture of products A, B and C

(A)
(B)
(C) CH3 – CH2 – CH2 – CH2 – Br

The mixture consists of:


Which of the following alkenes on ozonolysis give a mixture of ketones only?

(i) CH3 – CH = CH – CH3
(ii) \[\begin{array}{cc}
\ce{CH3 - C - CH = CH2}\\
|\phantom{.......}\\
\ce{CH3}\phantom{....}
\end{array}\]
(iii)
(iv) \[\begin{array}{cc}
\phantom{...................}\ce{CH3}\\
\phantom{..............}/\\
\ce{(CH3)2 C = C}\\
\phantom{..............}\backslash\\
\phantom{...................}\ce{CH3}
\end{array}\]

An alkene 'X' on ozonolysis produces two moles of isovaleraldehyde. Predict the IUPAC name of the alkene. 


Which of the following reagent is used for the following reaction?

\[\ce{CH3CH2CH3 ->[?] CH3CH2CHO}\]


The major product formed in the following reactions is:


Select schemes A, B, C out of

(I) acid catalysed hydration

(II) HBO

(III) oxymercuration-demercuration


What would be the main product when propene reacts with HBr?


Propene, \[\ce{CH3 - CH = CH2}\] can be converted to 1-propanol by oxidation. Which set of reagents among the following is ideal to effect the conversion ______.


3-Methyl-pent-2-ene on reaction with HBr in presence of peroxide forms an addition product. The number of possible stereoisomers for the product is ______.


In the presence of peroxide, HCl and HI do not give anti-Markovnikov's addition of alkenes because ______.


An alkene ‘A’ contains three C-C, eight C-H σ bonds and one C-C π bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write the IUPAC name of ‘A’.


Identify the correct reagents that would bring about the following transformation.


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