Advertisements
Advertisements
प्रश्न
On passing 1.5 F charge, the number of moles of aluminium deposited at cathode are _______ [Molar mass of Al = 27 gram mol–1]
(A) 1.0
(B) 13.5
(C) 0.50
(D) 0.75
Advertisements
उत्तर
(C) 0.50
The half reaction for the reduction of Al3+ ion is
Al3+ + 3e– → Al
The reaction indicate that 1 mole of Al is produced by the passage of 3 mole electrons. The charge of 3 mole electrons is 3 faraday.
3 F of charge produces 1 mole of Al.
1.5 F of charge produces 0.50 mole of Al.
APPEARS IN
संबंधित प्रश्न
On calculating the strength of current in amperes if a charge of 840C (coulomb) passes through an electrolyte in 7 minutes, it will be
- 1
- 2
- 3
- 4
The charge of how many coulomb is required to deposit 1.0 g of sodium metal (molar mass 23.0 g mol-1) from sodium ions is -
- 2098
- 96500
- 193000
- 4196
Write any four applications of electrochemical series
How much electricity in terms of Faraday is required to produce 20 g of Ca from molten CaCl2?
(Given: Molar mass of Calcium is 40 g mol−1.)
Number of faradays of electricity required to liberate 12 g of hydrogen is:
Following reactions occur at cathode during the electrolysis of aqueous sodium chloride solution:
Na+(aq) + e− ⟶ Na (s) E0 = 2.71 V
H+(aq) + e− ⟶ `1/2` H2 (g) E0 = 0.00 V
On the basis of their standard reduction electrode potential (E0) values, which reaction is feasible at the cathode and why?
Suggest a list of metals that are extracted electrolytically.
Consider the reaction:
\[\ce{Cr2O^{2-}_7 + 14H+ + 6e- -> 2Cr^{3+} + 7H2O}\]
What is the quantity of electricity in coulombs needed to reduce 1 mol of \[\ce{Cr2O^{2-}_7}\]?
How much charge is required for the following reduction?
1 mol of Al3+ to Al.
Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively, are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited?
Write any two uses of H2SO4
What is the ratio of volumes of H2 and O2 liberated during electrolysis of acidified water?
(A) 1 : 2
(B) 2 : 1
(C) 1 : 8
(D) 8 : 1
Explain Faraday’s second law of electrolysis
Following reactions occur at cathode during the electrolysis of aqueous copper(II) chloride solution :
On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why ?
How much quantity of electricity in coulomb is required to deposit 1.346 × 10-3 kg of Ag in 3.5 minutes from AgNO3 solution?
( Given: Molar mass of Ag is 108 × 10-3 kg mol-1 )
Solve the following question.
A steady current of 2 amperes was passed through two electrolytic cells X and Y connected in series containing electrolytes FeSO4 and ZnSO4 until 2.8 g of Fe deposited at the cathode of cell X. How long did the current flow? Calculate the mass of Zn deposited at the cathode of cell Y.
(Molar mass : Fe = 56 g mol–1, Zn = 65.3 g mol–1, 1F = 96500 C mol–1)
According to Faraday’s First Law of Electrolysis, the amount of chemical reaction which occurs at any electrode during electrolysis by a current is proportional to the ____________.
Aqueous copper sulphate solution and aqueous silver nitrate solution are electrolysed by 1 ampere current for 10 minutes in separate electrolytic cells. Will the mass of copper and silver deposited on the cathode be same or different? Explain your answer.
Assertion: Electrolysis of NaCl solution gives chlorine at anode instead of O2.
Reason: Formation of oxygen at anode requires overvoltage.
Consider the figure and answer the following question.
Cell ‘A’ has ECell = 2V and Cell ‘B’ has ECell = 1.1V which of the two cells ‘A’ or ‘B’ will act as an electrolytic cell. Which electrode reactions will occur in this cell?
The quantity of electricity needed to separately electrolyse 1 M solution of ZnSO4, AlCl3, and AgNO3 completely is in the ratio of ______.
A current of 4 amp was passed for 2 hours through a solution of copper sulphate when 5.0 g of copper was deposited. The current efficiency is ______% (Cu = 63.5).
On passing electricity through nitrobenzene solution, it is converted into azobenzene. The mass of azobenzene is ______ mg, if the same quantity of electricity produces oxygen just sufficient to burn 96 mg of fullerene (C60)·
Assertion (A): During electrolysis of aqueous copper sulphate solution using copper electrodes hydrogen gas is released at the cathode.
Reason (R): The electrode potential of Cu2+/Cu is greater than that of H+/H2.
Select the most appropriate answer from the options given below:
