Advertisements
Advertisements
प्रश्न
Explain Faraday’s second law of electrolysis
Advertisements
उत्तर
Explanation:
Two cells are connected in series. They contain different electrolytes. Same quantity of
electricity is passed through them. In other words, the number of moles of electrons passed
through two electrolytes is same.
Moles of A produced in one cell = moles of electrons actually passed × mole ratio of A half
reaction
Mole of B produced in other cell = moles of electrons actually passed × mole ratio of B half
reaction
Hence, `"moles of A produced"/"moles of B produced" = "mole ratio of A half reaction"/"mole ratio of B half reaction"`
APPEARS IN
संबंधित प्रश्न
The charge of how many coulomb is required to deposit 1.0 g of sodium metal (molar mass 23.0 g mol-1) from sodium ions is -
- 2098
- 96500
- 193000
- 4196
How much electricity in terms of Faraday is required to produce 20 g of Ca from molten CaCl2?
(Given: Molar mass of Calcium is 40 g mol−1.)
If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?
Consider the reaction: \[\ce{Cr2O^{2-}_7 + 14H^+ + 6e^- -> 2Cr^{3+} + 7H2O}\]
What is the quantity of electricity in coulombs needed to reduce 1 mol of \[\ce{Cr2O^{2-}_7}\]?
How much charge is required for the following reduction?
1 mol of Cu2+ to Cu.
How much charge is required for the following reduction:
1 mol of \[\ce{MnO^-_4}\] to Mn2+?
A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of 5 amperes for 20 minutes. What mass of Ni is deposited at the cathode?
On passing 1.5 F charge, the number of moles of aluminium deposited at cathode are _______ [Molar mass of Al = 27 gram mol–1]
(A) 1.0
(B) 13.5
(C) 0.50
(D) 0.75
Draw neat labelled diagram of electrolytic refining of blister copper
State second law of electrolysis
Write the name of the cell which is generally used in transistors. Write the reactions taking place at the anode and the cathode of this cell.
Following reactions occur at cathode during the electrolysis of aqueous copper(II) chloride solution :
On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why ?
Solve the following question.
A steady current of 2 amperes was passed through two electrolytic cells X and Y connected in series containing electrolytes FeSO4 and ZnSO4 until 2.8 g of Fe deposited at the cathode of cell X. How long did the current flow? Calculate the mass of Zn deposited at the cathode of cell Y.
(Molar mass : Fe = 56 g mol–1, Zn = 65.3 g mol–1, 1F = 96500 C mol–1)
In the electrolysis of aqueous sodium chloride solution which of the half cell reaction will occur at anode?
Aqueous copper sulphate solution and aqueous silver nitrate solution are electrolysed by 1 ampere current for 10 minutes in separate electrolytic cells. Will the mass of copper and silver deposited on the cathode be same or different? Explain your answer.
Assertion: Electrolysis of NaCl solution gives chlorine at anode instead of O2.
Reason: Formation of oxygen at anode requires overvoltage.
Time Required to deposite one millimole of aluminium metal by the passage of 9.65 ampere through aqueous solution of aluminium is
When during electrolysis of a solution of AgNO3, 9650 coulombs of charge pass through the electroplating bath, the mass of silver deposited on the cathode will be ______.
On electrolysis of dilute sulphuric acid using platinum electrodes, the product obtained at the anode will be ______.
What is the quantity of electricity in Coulombs required to produce 4.8 g of Mg from molten MgCl2? How much Ca will be produced if the same amount of electricity was passed through molten CaCl2? (Atomic mass of Mg = 24 u, atomic mass of Ca = 40 u).
A current of 4 amp was passed for 2 hours through a solution of copper sulphate when 5.0 g of copper was deposited. The current efficiency is ______% (Cu = 63.5).
On passing electricity through nitrobenzene solution, it is converted into azobenzene. The mass of azobenzene is ______ mg, if the same quantity of electricity produces oxygen just sufficient to burn 96 mg of fullerene (C60)·
Assertion (A): During electrolysis of aqueous copper sulphate solution using copper electrodes hydrogen gas is released at the cathode.
Reason (R): The electrode potential of Cu2+/Cu is greater than that of H+/H2.
Select the most appropriate answer from the options given below:
