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प्रश्न
Match the example given in Column I with the name of the reaction in Column II.
| Column I (Example) |
Column II (Reaction) |
||
| (i) | \[\begin{array}{cc} \phantom{...}\ce{O}\phantom{..............................}\ce{O}\phantom{}\\ \phantom{...}||\phantom{..............................}||\phantom{}\\ \ce{CH3 - C - Cl + H2 ->[Pd - C/BasO4] CH3 - C - H} \end{array}\] |
(a) | Friedel Crafts acylation |
| (ii) |  |
(b) | HVZ reaction |
| (iii) |  |
(c) | Aldol condensation |
| (iv) | \[\begin{array}{cc} \ce{R - CH2 - COOH ->[Br/Red P] R - CH - COOH}\\ \phantom{.....................}|\\ \phantom{.......................}\ce{Br} \end{array}\] |
(d) | Cannizaro’s reaction |
| (v) | \[\ce{CH3 - CN ->[(i) SnCl2/HCl][(ii) H2O/H+] CH3CHO}\] | (e) | Rosenmund’s reductio |
| (vi) | \[\ce{2CH3CHO ->[NaOH] CH3 - CH = CHCHO}\] | (f) | Stephen’s reaction |
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उत्तर
| Column I (Example) |
Column II (Reaction) |
||
| (i) | \[\begin{array}{cc} \phantom{...}\ce{O}\phantom{..............................}\ce{O}\phantom{}\\ \phantom{...}||\phantom{..............................}||\phantom{}\\ \ce{CH3 - C - Cl + H2 ->[Pd - C/BasO4] CH3 - C - H} \end{array}\] |
(e) | Rosenmund’s reductio |
| (ii) | |
(d) | Cannizaro’s reaction |
| (iii) | |
(a) | Friedel Crafts acylation |
| (iv) | \[\begin{array}{cc} \ce{R - CH2 - COOH ->[Br/Red P] R - CH - COOH}\\ \phantom{.....................}|\\ \phantom{.......................}\ce{Br} \end{array}\] |
(b) | HVZ reaction |
| (v) | \[\ce{CH3 - CN ->[(i) SnCl2/HCl][(ii) H2O/H+] CH3CHO}\] | (f) | Stephen’s reaction |
| (vi) | \[\ce{2CH3CHO ->[NaOH] CH3 - CH = CHCHO}\] | (c) | Aldol condensation |
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संबंधित प्रश्न
Write the product in the following reaction
Write the product in the following reaction:
Write the chemical equations to illustrate the following name reactions : Rosenmund reduction
Write the structure of the product of the following reaction:
Write the reaction involved in the Stephen reduction
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Aldehydes are produced on reduction of the following by DIBAL-H:
The oxidation of toluene to benzoic acid can be done using which of the following reagents.
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\[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH3}\\
\phantom{.....}|\\
\phantom{......}\ce{Cl}
\end{array}\] obtained by chlorination of n-butane, will be
When 2 – hydroxyl benzoic acid distilled with zinc dust, it give
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Reason (R): It is possible to stop the oxidation of toluene at the aldehyde stage with suitable reagents.
Select the most appropriate answer from the options given below:
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Account for the following:
Reduction of nitrobenzene using Fe and HCl is preferred over Sn and HCl.
Write the name of the reaction, structure and IUPAC name of the product formed when:
CH3CH2CN reacts with stannous chloride in the presence of hydrochloric acid, followed by hydrolysis.
