Advertisements
Advertisements
प्रश्न
In a diatomic molecule, the rotational energy at a given temperature ______.
- obeys Maxwell’s distribution.
- have the same value for all molecules.
- equals the translational kinetic energy for each molecule.
- is (2/3)rd the translational kinetic energy for each molecule.
Advertisements
उत्तर
a and d
Explanation:
Consider a diatomic molecule as shown in the diagram.
The total energy associated with the molecule is
`E = 1/2 mv_x^2 + 1/2 mv_y^2 + 1/2 mv_z^2 + 1/2 I_xω_x^2 + 1/2 I_yω_y^2`
This above expression contains translational kinetic energy `(1/2 mv^2)` corresponding to velocity in each x, y and z-directions as well as rotational KE `(1/2 Iω^2)` associated with the axis of rotations x and y.
The number of independent terms in the above expression is 5.
As we can predict the velocities of molecules by Maxwell's distribution, hence the above expression also obeys Maxwell's distribution.
∵ 2 rotational and 3 translational energies are associated with each molecule.
∴ Rational energy at a given temperature is `(2/3)`rd of translational KE of each molecule.
APPEARS IN
संबंधित प्रश्न
The energy of a given sample of an ideal gas depends only on its
A sample of 0.177 g of an ideal gas occupies 1000 cm3 at STP. Calculate the rms speed of the gas molecules.
Let Q and W denote the amount of heat given to an ideal gas and the work done by it in an isothermal process.
A rigid container of negligible heat capacity contains one mole of an ideal gas. The temperature of the gas increases by 1° C if 3.0 cal of heat is added to it. The gas may be
(a) helium
(b) argon
(c) oxygen
(d) carbon dioxide
The figure shows a cylindrical container containing oxygen (γ = 1.4) and closed by a 50-kg frictionless piston. The area of cross-section is 100 cm2, atmospheric pressure is 100 kPa and g is 10 m s−2. The cylinder is slowly heated for some time. Find the amount of heat supplied to the gas if the piston moves out through a distance of 20 cm.
The ratio of the molar heat capacities of an ideal gas is Cp/Cv = 7/6. Calculate the change in internal energy of 1.0 mole of the gas when its temperature is raised by 50 K (a) keeping the pressure constant (b) keeping the volume constant and (c) adiaba
An ideal gas (Cp / Cv = γ) is taken through a process in which the pressure and the volume vary as p = aVb. Find the value of b for which the specific heat capacity in the process is zero.
Half mole of an ideal gas (γ = 5/3) is taken through the cycle abcda, as shown in the figure. Take `"R" = 25/3"J""K"^-1 "mol"^-1 `. (a) Find the temperature of the gas in the states a, b, c and d. (b) Find the amount of heat supplied in the processes ab and bc. (c) Find the amount of heat liberated in the processes cd and da.
An ideal gas (γ = 1.67) is taken through the process abc shown in the figure. The temperature at point a is 300 K. Calculate (a) the temperatures at b and c (b) the work done in the process (c) the amount of heat supplied in the path ab and in the path bcand (d) the change in the internal energy of the gas in the process.
An ideal gas at pressure 2.5 × 105 Pa and temperature 300 K occupies 100 cc. It is adiabatically compressed to half its original volume. Calculate (a) the final pressure (b) the final temperature and (c) the work done by the gas in the process. Take γ = 1.5
1 litre of an ideal gas (γ = 1.5) at 300 K is suddenly compressed to half its original volume. (a) Find the ratio of the final pressure to the initial pressure. (b) If the original pressure is 100 kPa, find the work done by the gas in the process. (c) What is the change in internal energy? (d) What is the final temperature? (e) The gas is now cooled to 300 K keeping its pressure constant. Calculate the work done during the process. (f) The gas is now expanded isothermally to achieve its original volume of 1 litre. Calculate the work done by the gas. (g) Calculate the total work done in the cycle.
Figure shows a cylindrical tube with adiabatic walls and fitted with an adiabatic separator. The separator can be slid into the tube by an external mechanism. An ideal gas (γ = 1.5) is injected in the two sides at equal pressures and temperatures. The separator remains in equilibrium at the middle. It is now slid to a position where it divides the tube in the ratio 1 : 3. Find the ratio of the temperatures in the two parts of the vessel.
Two vessels A and B of equal volume V0 are connected by a narrow tube that can be closed by a valve. The vessels are fitted with pistons that can be moved to change the volumes. Initially, the valve is open and the vessels contain an ideal gas (Cp/Cv = γ) at atmospheric pressure p0 and atmospheric temperature T0. The walls of vessel A are diathermic and those of B are adiabatic. The valve is now closed and the pistons are slowly pulled out to increase the volumes of the vessels to double the original value. (a) Find the temperatures and pressures in the two vessels. (b) The valve is now opened for sufficient time so that the gases acquire a common temperature and pressure. Find the new values of the temperature and pressure.
The figure shows an adiabatic cylindrical tube of volume V0 divided in two parts by a frictionless adiabatic separator. Initially, the separator is kept in the middle, an ideal gas at pressure p1 and temperature T1 is injected into the left part and another ideal gas at pressure p2 and temperature T2 is injected into the right part. Cp/Cv = γ is the same for both the gases. The separator is slid slowly and is released at a position where it can stay in equilibrium. Find (a) the volumes of the two parts (b) the heat given to the gas in the left part and (c) the final common pressure of the gases.
An ideal gas of density 1.7 × 10−3 g cm−3 at a pressure of 1.5 × 105 Pa is filled in a Kundt's tube. When the gas is resonated at a frequency of 3.0 kHz, nodes are formed at a separation of 6.0 cm. Calculate the molar heat capacities Cp and Cv of the gas.
1 mole of an ideal gas is contained in a cubical volume V, ABCDEFGH at 300 K (Figure). One face of the cube (EFGH) is made up of a material which totally absorbs any gas molecule incident on it. At any given time ______.
ABCDEFGH is a hollow cube made of an insulator (Figure). Face ABCD has positive charge on it. Inside the cube, we have ionized hydrogen. The usual kinetic theory expression for pressure ______.
- will be valid.
- will not be valid since the ions would experience forces other than due to collisions with the walls.
- will not be valid since collisions with walls would not be elastic.
- will not be valid because isotropy is lost.
Diatomic molecules like hydrogen have energies due to both translational as well as rotational motion. From the equation in kinetic theory `pV = 2/3` E, E is ______.
- the total energy per unit volume.
- only the translational part of energy because rotational energy is very small compared to the translational energy.
- only the translational part of the energy because during collisions with the wall pressure relates to change in linear momentum.
- the translational part of the energy because rotational energies of molecules can be of either sign and its average over all the molecules is zero.
