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प्रश्न
Illustrate the following reactions giving suitable example in each case
Ammonolysis
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उत्तर
Ammonolysis: When an alkyl or benzyl halide is allowed to react with an ethanolic solution of ammonia, it undergoes a nucleophilic substitution reaction in which the halogen atom is replaced by an amino (−NH2) group. This process of cleavage of the carbon–halogen bond is known as ammonolysis.
For example, the ammonolysis of chloroethane yields a substituted ammonium salt.
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संबंधित प्रश्न
Give reasons for the following: (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Arrange the following in increasing order of their basic strength :
C6H5 – NH2, C6H5 – CH2 – NH2, C6H5 – NH – CH3
- Write structures of different isomeric amines corresponding to the molecular formula C4H11N.
- Write the IUPAC names of all the isomers.
- What type of isomerism is exhibited by different pairs of amines?
Arrange the following in increasing order of their basic strength:
C2H5NH2, C6H5NH2, NH3, C6H5CH2NH2 and (C2H5)2NH
Accomplish the following conversion:
Aniline to p-bromoaniline
Arrange the following in the increasing order of their pKb values:
C6H5NH2, C2H5NH2, C6H5NHCH3
The CORRECT decreasing order of solubility in water will be ____________.
Which among the following has the highest boiling point?
Among the following isomeric amines, an amine having highest boiling point is:
Account for the following:
N-ethylethanamine boils at 329.3 K and butanamine boils at 350.8 K, although both are isomeric in nature.
