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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता ११ वी

Distinguish between Inductive effect and resonance effect.

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प्रश्न

Distinguish between Inductive effect and resonance effect.

फरक स्पष्ट करा
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उत्तर

  Inductive effect Resonance effect
1. The presence of a polar covalent bond is required. The presence of a conjugated π electron system or species having an atom carrying p orbital attached to multiple bonds is required.
2. The polarity is induced in adjacent carbon-carbon single (covalent) bonds due to the presence of an influencing group (more electronegative atom than carbon). The polarity is produced in the molecule by the interaction of conjugated π bonds (or that between π bond and p orbital on the adjacent atom).
3. Depending on the nature of the influencing group it is differentiated as +I effect and -I effect. Depending on the nature of the influencing group it is differentiated as +R and -R effect.
4. The direction of the arrow head denotes the direction of the permanent electron displacement. The delocalisation of π electrons is denoted by using curved arrows.
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Theoretical Basis of Organic Reactions
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 14: Basic Principles of Organic Chemistry - Exercises [पृष्ठ २३१]

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बालभारती Chemistry [English] Standard 11 Maharashtra State Board
पाठ 14 Basic Principles of Organic Chemistry
Exercises | Q 7. A. | पृष्ठ २३१

संबंधित प्रश्‍न

Find out the most stable species from the following. Justify 

`dot"CH","CH"_3-dot"CH" - "CH"_3,` \[\begin{array}{cc}\ce{CH3 -\dot{C} - CH3}\\
|\phantom{.}\\\phantom{..}\ce{CH3}\end{array}\]


Find out the most stable species from the following. Justify.

`bar"C""H"_3, bar"C""H"_2"Br", bar"C""Br"_3`


Identify the α - carbons in the following species and give the total number of α-hydrogen.


Identify the α-carbon in the following species and give the total number of α-hydrogens.

\[\ce{CH2 = CH - CH2 - CH3}\]


Write true or false. Correct the false statement.

Heterolytic fission results in the formation of free radicals.


Choose the correct option.

Hyperconjugation involves overlap of ______ orbitals.


Which of the following statements is INCORRECT about hyperconjugation?


Which among the following is a set of nucleophiles?


The +I inductive effect is shown by which of the following groups?


Which of the following alkyl groups shows maximum positive inductive effect?


The overlap of σ-p orbitals is called ____________.


IUPAC name of is ______.


Which of the following alkyl groups shows least positive inductive effect?


How many tertiary carbon atoms and primary carbon atoms respectively are present in 2-iodo-3, 3- dimethyl pentane?


How many pi bonds and sigma bonds are present in following molecule?


Which element among the following does form pπ - pπ multiple bonds?


Arrange the following free radicals in order of decreasing stability.

  1. Methyl
  2. Vinyl
  3. Allyl
  4. Benzyl

Identify the α-carbons in the following species and give the total number of α-hydrogen.  

\[\ce{CH2 = CH - CH2 - CH3}\]


Identify the α-carbons in the following species and give the total number of α-hydrogen.

\[\ce{CH2 = CH - CH2 - CH3}\]


Identify the α-carbons in the following species and give the total number of α-hydrogen in it.

CH2 = CH − CH2 − CH3


Identify the α - carbons in the following species and give the total number of α-hydrogen.

\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]


Identify the α-carbon in the following species and give the total number of α-hydrogen.

\[\ce{CH2 = CH - CH2 - CH3}\]


Identify the α-carbons in the following species and give the total number of α-hydrogen.

\[\ce{CH2 = CH - CH2 - CH3}\]


Identify the α - carbons in the following species and give the total number of α-hydrogen in each.

\[\ce{CH3 - CH2 - \overset{\oplus}{C}H - CH2 - CH3}\]


Identify the α-carbons in the following species and give the total number of α-hydrogens.

\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]


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