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Following reactions occur at cathode during the electrolysis of aqueous silver chloride solution :
`Ag^+(aq)+e^(-)rarrAg(s)" "" "" "E^@=+0.80V`
`H^+(aq)+e^(-)rarr1/2H_2(g)" "" "" " E^@=0.00V`
On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why ?
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3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62 K. Calculate the van't Hoff factor and predict the nature of solute (associated or dissociated).
(Given : Molar mass of benzoic acid = 122 g mol−1, Kf for benzene = 4.9 K kg mol−1)
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An element with molar mass 27 g mol−1 forms a cubic unit cell with edge length 4.05 ✕ 10−8 cm. If its density is 2.7 g cm−3, what is the nature of the cubic unit cell?
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Calculate ΔrG° for the reaction
Mg (s) + Cu2+ (aq) → Mg2+ (aq) + Cu (s)
Given : E°cell = + 2.71 V, 1 F = 96500 C mol–1
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Describe the following:
Cannizzaro reaction
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Write any ‘two’ advantages of calomel electrode.
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Arrange the following oxyacids of chlorine – HClO, HClO2, HClO3, and HClO4 with respect to Increasing order of thermal stability.
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The secondary structure of protein is determined by _______.
(A) co-ordinate bond
(B) ionic bond
(C) hydrogen bond
(D) covalent bond
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Write names and chemical formulae of monomers used in preparing Buna-N.
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Explain optical activity of lactic acid
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Explain with reason sign conventions of ΔS in the following reaction
N2(g) + 3H2(g) → 2NH3(g)
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Explain with reason sign conventions of ΔS in the following reaction
CO2(g) → CO2(g)
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Potential of saturated calomel electrode is-
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A face centred cube (FCC) consists of how many atoms? Explain
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What happens when thin copper leaves are thrown in jar containing chlorine?
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Write the formulae of the raw materials used for preparation of Buna-S
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Write four postulates of Werner's theory.
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How are the following conversions carried out?
2-methylbutan-1-ol into 2 -methylbutanoic acid.
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What is the action of chlorine (Cl) on the following:
Cold and dilute caustic soda
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What is the action of chlorine (Cl) on the following:
Hot and concentrated caustic soda
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