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Give the equations of reactions for the preparation of phenol from cumene.
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Write chemical reaction for the preparation of phenol from chlorobenzene.
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You are given benzene, conc. H2SO4 and NaOH. Write the equations for the preparation of phenol using these reagents.
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Write the equation for the preparation of 1-iodobutane from but-1-ene.
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How will you bring about the following conversion?
Ethane to bromoethene
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How the following conversion can be carried out?
Aniline to chlorobenzene
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What happens when white phosphorus is heated with concentrated NaOH solution in an inert atmosphere of CO2?
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Give reasons CH3NH2 is more basic than C6H5NH2.
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Following data are obtained for reaction :
N2O5 → 2NO2 + 1/2O2
| t/s | 0 | 300 | 600 |
| [N2O5]/mol L–1 | 1.6 × 10-2 | 0.8 × 10–2 | 0.4 × 10–2 |
1) Show that it follows first order reaction.
2) Calculate the half-life.
(Given log 2 = 0.3010, log 4 = 0.6021)
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An element has atomic mass 93 g mol−1 and density 11.5 g cm–3. If the edge length of its unit cell is 300 pm, identify the type of unit cell. (NA = 6.023 × 1023 mol−1)
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Calculate the number of unit cells in 8.1 g of aluminium if it crystallizes in a f.c.c. structure. (Atomic mass of Al = 27 g mol–1)
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Give reason for the following:
Red phosphorus is less reactive than white phosphorus.
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A first order reaction takes 20 minutes for 25% decomposition. Calculate the time when 75% of the reaction will be completed.
(Given : log = 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021)
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Give reasons for the following :
Aquatic animals are more comfortable in the cold water than in warm water.
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Write the chemical reactions involved in the process of extraction of Gold. Explain the role of dilute NaCN and Zn in this process.
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Write the product when D-glucose reacts with conc. HNO3.
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Give reason (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
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An element 'X' (At. mass = 40 g mol-1) having f.c.c. the structure has unit cell edge length of 400 pm. Calculate the density of 'X' and the number of unit cells in 4 g of 'X'. (NA = 6.022 × 1023 mol-1)
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Arrange the following in the increasing order of their pKb values:
C6H5NH2, C2H5NH2, C6H5NHCH3
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Which allotrope of sulphur is thermally stable at room temperature ?
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