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प्रश्न
Write the structure of the product of the following reaction:
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उत्तर
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संबंधित प्रश्न
How will you bring about the following conversion?
Benzoyl chloride to benzaldehyde.
Predict the product of the following reaction:
Write the reaction involved in the Stephen reduction
Ozonolysis of alkenes followed by the reaction with zinc dust and water gives ____________ depending on the substitution pattern of the alkene.
Esters react with DIBAL-H to produce:
Aldehydes are produced on reduction of the following by DIBAL-H:
The oxidation of toluene to benzoic acid can be stopped at the aldehyde stage to give benzaldehyde. The reagent used for the purpose is one of the following.
Aldehydes are prepared by reducing nitriles to corresponding imines with stannous chloride in the presence of hydrochloric acid. This reaction is called:
Match the acids given in Column I with their correct IUPAC names given in Column II.
| Column I (Acids) |
Column II (IUPAC names) |
||
| (i) | Phthalic acid | (a) | Hexane-1,6-dioic acid |
| (ii) | Oxalic acid | (b) | Benzene-1,2-dicarboxylic acid |
| (iii) | Succinic acid | (c) | Pentane-1,5-dioic acid |
| (iv) | Adipic acid | (d) | Butane-1,4-dioic acid |
| (v) | Glutaric acid | (e) | Ethane-1,2-dioic acid |
Match the example given in Column I with the name of the reaction in Column II.
| Column I (Example) |
Column II (Reaction) |
||
| (i) | \[\begin{array}{cc} \phantom{...}\ce{O}\phantom{..............................}\ce{O}\phantom{}\\ \phantom{...}||\phantom{..............................}||\phantom{}\\ \ce{CH3 - C - Cl + H2 ->[Pd - C/BasO4] CH3 - C - H} \end{array}\] |
(a) | Friedel Crafts acylation |
| (ii) |  |
(b) | HVZ reaction |
| (iii) |  |
(c) | Aldol condensation |
| (iv) | \[\begin{array}{cc} \ce{R - CH2 - COOH ->[Br/Red P] R - CH - COOH}\\ \phantom{.....................}|\\ \phantom{.......................}\ce{Br} \end{array}\] |
(d) | Cannizaro’s reaction |
| (v) | \[\ce{CH3 - CN ->[(i) SnCl2/HCl][(ii) H2O/H+] CH3CHO}\] | (e) | Rosenmund’s reductio |
| (vi) | \[\ce{2CH3CHO ->[NaOH] CH3 - CH = CHCHO}\] | (f) | Stephen’s reaction |
What is the name of the given reaction of preparation of aldehyde?
\[\ce{C3COCl ->[H2][Pd/BaSO4] CH3CHO + HCl}\]
In the chromyl chloride test, the final step results in the formation of a yellow precipitate of the following:
The general formula CnH2NO2 could be for open chain
Aldehydes are the first oxidation products of ______.
The reagent in friedel - craft reaction is:
Convert the following:
Benzoic acid to Benzaldehyde.
Explain the following reactions:
Stephan reaction
Reagent used to convert allyl alcohol to acrolein is ______.
Account for the following:
Reduction of nitrobenzene using Fe and HCl is preferred over Sn and HCl.
Write the name of the reaction, structure and IUPAC name of the product formed when:
CH3CH2CN reacts with stannous chloride in the presence of hydrochloric acid, followed by hydrolysis.
