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प्रश्न
Predict the reagent for carrying out the following transformations:
Benzoyl chloride to Benzaldehyde
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उत्तर
Rosenmund Reduction in presence of Lindlar's Catalyst (H2/Pd-BaSO4).
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संबंधित प्रश्न
How will you bring about the following conversion?
Benzoyl chloride to benzaldehyde.
Predict the product of the following reaction:
Ozonolysis of alkenes followed by the reaction with zinc dust and water gives ____________ depending on the substitution pattern of the alkene.
The oxidation of toluene to benzoic acid can be done using which of the following reagents.
Name the electrophile produced in the reaction of benzene with benzoyl chloride in the presence of anhydrous \[\ce{AlCl3}\]. Name the reaction also.
Match the common names given in Column I with the IUPAC names given in Column II.
| Column I (Common names) |
Column II (IUPAC names) |
||
| (i) | Cinnamaldehyde | (a) | Pentanal |
| (ii) | Acetophenone | (b) | Prop-2-enal |
| (iii) | Valeraldehyde | (c) | 4-Methylpent-3-en-2-one |
| (iv) | Acrolein | (d) | 3-Phenylprop-2-enal |
| (v) | Mesityl oxide | (e) | 1-Phenylethanone |
Match the example given in Column I with the name of the reaction in Column II.
| Column I (Example) |
Column II (Reaction) |
||
| (i) | \[\begin{array}{cc} \phantom{...}\ce{O}\phantom{..............................}\ce{O}\phantom{}\\ \phantom{...}||\phantom{..............................}||\phantom{}\\ \ce{CH3 - C - Cl + H2 ->[Pd - C/BasO4] CH3 - C - H} \end{array}\] |
(a) | Friedel Crafts acylation |
| (ii) |  |
(b) | HVZ reaction |
| (iii) |  |
(c) | Aldol condensation |
| (iv) | \[\begin{array}{cc} \ce{R - CH2 - COOH ->[Br/Red P] R - CH - COOH}\\ \phantom{.....................}|\\ \phantom{.......................}\ce{Br} \end{array}\] |
(d) | Cannizaro’s reaction |
| (v) | \[\ce{CH3 - CN ->[(i) SnCl2/HCl][(ii) H2O/H+] CH3CHO}\] | (e) | Rosenmund’s reductio |
| (vi) | \[\ce{2CH3CHO ->[NaOH] CH3 - CH = CHCHO}\] | (f) | Stephen’s reaction |
The oxidation of toluene to benzaldehyde by chromyl chloride is called ______.
The reaction of benzene with CO and HCl in the presence of anhydrous AlCl3 gives ______.
Reagent used to convert allyl alcohol to acrolein is ______.
