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Write applications of Kohlrausch’s Law.

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प्रश्न

Write applications of Kohlrausch’s Law.

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उत्तर

  1. The theory can be used to calculate the molar conductivity of an electrolyte at the zero concentration.
  2. Determination of molar conductivity of weak electrolyte at zero concentration.
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अध्याय 5: Electrochemistry - Short answer questions (Type- I)

संबंधित प्रश्न

0.05 M NaOH solution offered a resistance of 31.6 Ω in a conductivity cell at 298 K. If the cell constant of the cell is 0.367 cm-1, calculate the molar conductivity of NaOH solution.


What is a cell constant? What are its units? How is it determined experimentally?


Kohlrausch law is applicable for the solution _______.


SI unit of conductivity is _______.


Give SI unit of resistivity.


Calculate molar conductivities at zero concentration for CaCl2 and NaCl.

Given: molar ionic conductivities of Ca2+, Cl, Na+ ions are respectively, 104, 76.4, 50.1 Ω–1 cm–2 mol–1


The CORRECT unit of molar conductivity is ____________.


What will be the concentration of NaCl solution, if the molar conductivity and conductivity of NaCl solution is 124.3 Ω−1 cm2 mol−1 and 1.243 × 10−4 Ω−1 cm2 respectively?


The molar conductance of 0.001 M acetic acid is 50 ohm−1 cm2 mol−1. The limiting molar conductance is 250 ohm−1 cm2 mol−1. What is its degree of ionization?


The molar conductivities at zero concentration for Ca2+ and CaCl2 are 104 and 256.8 Ω−1 cm2 mol−1 respectively. The molar conductivity at zero concentration for Cl is ____________.


The molar conductivities at infinite dilution for sodium acetate, HCI and NaCl are 91 S cm2 mol-1, 425.9 S cm2 mol-1 and 126.4 S cm2 mol-1 respectively. The molar conductivity of acetic acid at infinite dilution is ______.


Which of the following graph represents the variation of `∧` with `sqrt"c"` for acetic acid solution?


What is the cell constant of `"N"/10 "KCl"` solution at 25°C, if conductivity and resistance of a solution is 0.0112 Ω−1 cm−1 and 55.0 Ω respectively?


Conductivity of a conductor is ____________.


A conductivity cell dipped in 0.01 M AgNO3 solution gives a resistance of 3160 ohms. If cell constant is 0.47 cm−1, what is the conductivity of AgNO3 solution?


What is the unit of electrical conductance?


A conductivity cell dipped in 0.5 M KCl gives a resistance of 250 ohms. If the conductivity of KC I solution is 6.68 × 10-3 S cm-1, what is the cell constant?


If the resistivity of 0.1 M KCI solution is 50 Ω cm, what is it's molar conductivity?


Which of the following has least conductivity in aqueous solution? 


Molar conductivities at infinite dilution of Mg2+ and Br- are 105.8 Ω-1 cm2 mol-1 and 78.2 Ω-1 cm2 mol-1 respectively. Calculate molar conductivity at zero concentration of MgBr2.


A conductivity cell filled with 0.02 M AgNO3 gives at 25°C resistance of 947 ohms. If the cell constant is 2.3 cm-1, what is the molar conductivity of 0.02 M AgNO3 at 25°C?


Explain the determination of molar conductivity of a weak electrolyte at infinite dilution or zero concentration using Kohlrausch's law.


Define the term cell constant.


The resistance of a conductivity cell with cell constant 1.14 cm−1, containing 0.001 M KCl at 298 K is 1500 Ω. The molar conductivity of 0.001 MKCl solution at 298 K in S cm2 mol−1 is ______. (Integer answer)


Two solutions have the ratio of their concentrations 0.4 and ratio of their conductivities 0.216. What is the ratio of their molar conductivities?


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