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प्रश्न
Write applications of Kohlrausch’s Law.
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उत्तर
- The theory can be used to calculate the molar conductivity of an electrolyte at the zero concentration.
- Determination of molar conductivity of weak electrolyte at zero concentration.
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संबंधित प्रश्न
0.05 M NaOH solution offered a resistance of 31.6 Ω in a conductivity cell at 298 K. If the cell constant of the cell is 0.367 cm-1, calculate the molar conductivity of NaOH solution.
Answer the following in one or two sentences.
Write the relationship between conductivity and molar conductivity and hence unit of molar conductivity.
Kohlrausch law is applicable for the solution _______.
SI unit of conductivity is _______.
The molar conductivity and conductivity of AgNO3 solution is 121.4 Ω–1 cm2 mol–1 and 2.428 × 10–3 Ω–1 cm–1 at 25 °C. What is molar concentration of AgNO3 solution?
Give SI unit of resistivity.
Write an equation that shows the relationship between molar conductivity and degree of dissociation of weak electrolyte.
Calculate molar conductivities at zero concentration for CaCl2 and NaCl.
Given: molar ionic conductivities of Ca2+, Cl–, Na+ ions are respectively, 104, 76.4, 50.1 Ω–1 cm–2 mol–1
Molar conductance of BaCl2, H2SO4 and HCl at infinite dilution are X1, X2 and X3 respectively. Molar conductance of BaSO4 at infinite dilution is ____________.
The molar conductances at infinite dilution `(∧_0)` for electrolytes B+A− and C+A− are 140 and 120 S cm2 mol−1. The molar conductance at infinite dilution for B+X− is 198 S cm2 mol−1. The `∧_0` (in S cm2 mol−1) of C+X− is __________.
The conductivity of 0.02 M solution of NaCl is 2.6 × 10−2 S cm−1. What is its molar conductivity?
The molar conductivities at zero concentration for Ca2+ and CaCl2 are 104 and 256.8 Ω−1 cm2 mol−1 respectively. The molar conductivity at zero concentration for Cl− is ____________.
The molar conductivities at infinite dilution for sodium acetate, HCI and NaCl are 91 S cm2 mol-1, 425.9 S cm2 mol-1 and 126.4 S cm2 mol-1 respectively. The molar conductivity of acetic acid at infinite dilution is ______.
What is the common unit of conductivity if the dimensions are expressed in centimeter?
Which of the following graph represents the variation of `∧` with `sqrt"c"` for acetic acid solution?
What is the cell constant of `"N"/10 "KCl"` solution at 25°C, if conductivity and resistance of a solution is 0.0112 Ω−1 cm−1 and 55.0 Ω respectively?
The distance between electrodes of a conductivity cell is 0.98 cm and area of cross section is 1.96 cm2. What is the cell constant?
A conductivity cell dipped in 0.01 M AgNO3 solution gives a resistance of 3160 ohms. If cell constant is 0.47 cm−1, what is the conductivity of AgNO3 solution?
A conductivity cell dipped in 0.5 M KCl gives a resistance of 250 ohms. If the conductivity of KC I solution is 6.68 × 10-3 S cm-1, what is the cell constant?
What is the SI unit of conductivity?
A conductivity cell filled with 0.02 M AgNO3 gives at 25°C resistance of 947 ohms. If the cell constant is 2.3 cm-1, what is the molar conductivity of 0.02 M AgNO3 at 25°C?
Write the relation between molar conductivity and molar ionic conductivities for the electrolytes:
- Na2SO4
- AlCl3
Specific conductance of 0.1 M HNO3 is 6.3 × 10−2 ohm−1 cm−1. The molar conductance of the solution is ______.
When electric current is passed through acidified water, 112 mL of hydrogen gas at STP collected at the cathode in 965 seconds. The current passed in amperes is ______.
The molar conductivity of a 0.02 mol dm−3 solution of sodium hydroxide is 230.5 Ω−1 cm2 mol−1. What is its conductivity?
Two solutions have the ratio of their concentrations 0.4 and ratio of their conductivities 0.216. What is the ratio of their molar conductivities?
