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प्रश्न
Write an application of Hess’s law.
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उत्तर १
The Hess's law has been useful to calculate the enthalpy changes for the reactions with their enthalpies being not known experimentally.
उत्तर २
- It helps in calculating the enthalpies of formation of those compounds which cannot be determined experimentally.
- It helps in determining the enthalpy of allotropic transformation like C(graphite)→C(diamond)
- It helps in calculating the enthalpy of hydration.
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संबंधित प्रश्न
Answer the following question.
State Hess’s law of constant heat summation. Illustrate with an example. State its applications.
Calculate enthalpy of formation of HCl if bond enthalpies of H2, Cl2 and HCl are 434 kJ mol-1, 242 kJ mol–1 and 431 kJ mol–1 respectively.
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Calculate the standard enthalpy of the reaction.
\[\ce{2Fe_{(s)} + \frac{3}{2} O_{2(g)} -> Fe2O_{3(s)}}\]
Given:
| 1. | \[\ce{2Al_{(s)} + Fe2O_{3(s)} -> 2Fe_{(s)} + Al_2O_{3(s)}}\], | ∆rH° = –847.6 kJ |
| 2. | \[\ce{2Al_{(s)} + \frac{3}{2} O_{2(g)} -> Al2O_{3(s)}}\], | ∆rH° = –1670 kJ |
Define the Enthalpy of ionisation.
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Daily requirement of energy of a person is 'x' kJ. If heat of combustion of food material (Molecular mass = 100 g) is 'y' kJ, his daily consumption of the food in gram would be ____________.
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\[\ce{S + 3/2O2 -> SO3 +2{x} kcal}\] .........(i)
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The heat of formation of SO2 is ____________.
Which among the following salts, solubility decreases with increase in temperature?
Which of the following compounds is Not present in its standard state at 25°C and 1 atmosphere pressure?
Given the reaction,
\[\ce{CH2O_{(g)} + O2_{(g)} -> CO2_{(g)} + H2O_{(g)}}\] ΔH = −527 kJ
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Standard entropies of N2(g), H2(g), and NH3(g) are a1, a2 and a3 J K-1 mol-1 respectively. What is value of ΔS° for formation of NH3(g)?
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The enthalpy change that accompanies a reaction in which 1 mole of its standard state is formed from its elements in their standard states
Standard enthalpy of combustion of a substance is given. Then Write thermochemical equation.
ΔcH0[C2H5OH(1)] = - 1409 kJ mol-1
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For the reaction, aA + bB → cC + dD, write the expression for enthalpy change of reaction in terms of enthalpies of formation of reactants and products.
The enthalpy of combustion of S (rhombic) is − 297 kJ mo1-1. Calculate the amount of sulphur required to produce 29. 74 kJ of heat.
The heat evolved in the combustion of 6.022 x 1021 carbon particles is 3.94 kJ. The heat of combustion of carbon is ______.
For the reaction, H2 + I2 ⇌ 2HI; ΔH = 12.4 kcal. The heat of formation of HI, ΔHf = ______.
Calculate ΔsubH of the H2O from the given data:
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\[\ce{H2O_{(l)}-> H2O_{(g)},}\] ΔVapH = 45.07 kJ mol−1.
Calculate heat evolved for combustion of 13 gm of acetylene (C2H2).
Given: \[\ce{C2H2_{(g)} + 5/2O_{2(g)}-> 2CO_{2(g)} + H2O_{(l)} \Delta_{(c)}H^{0} = - 1300 kJ}\]
Calculate the standard enthalpy of combustion of methane if the standard enthalpy of formation of methane, carbon dioxide and water are −74.8, −393.5 and −285.8 kJmol−1 respectively.
