Advertisements
Advertisements
प्रश्न
Two samples A and B, of the same gas have equal volumes and pressures. The gas in sample A is expanded isothermally to double its volume and the gas in B is expanded adiabatically to double its volume. If the work done by the gas is the same for the two cases, show that γ satisfies the equation 1 − 21−γ = (γ − 1) ln2.
Advertisements
उत्तर
Let,
Initial pressure of the gas = P1
Initial volume of the gas = V1
Final pressure of the gas= P2
Final volume of the gas = V2
Given, V2 = 2 V1, for each case.
In an isothermal expansion process,
work done = `"n""R""T"_1 "l""n" "V"_2/"V"_1" `
Adiabatic work done,
`"W" = ("P"_1"V"_1 - "P"_2"V"_2)/ (gamma -1 )`
It is given that same work is done in both cases.
So,
`"n""R""T"_1 "l""n" ("V"_2/"V"_1) =( "P"_1 "V"_1 - "P"_2"V"_2)/ (gamma -1)` ..(1)
In an adiabatic process,
`"P"_2 = "P"_1 ("V"_1/"V"_2)^gamma ="P"_1(1/2)^gamma`
From eq (1),
`"n""R""T"_1 "l""n" 2 = ("P"_1"V"_1(1-1/2^gamma xx 2)) /(gamma -1)`
and nRT1 = P1V1
So, ln 2 =` (1 - 1/(2^gamma) . 2)/ (gamma -1)`
Or (γ − 1) ln 2 = 1 − 21−γ
APPEARS IN
संबंधित प्रश्न
The energy of a given sample of an ideal gas depends only on its
Keeping the number of moles, volume and temperature the same, which of the following are the same for all ideal gases?
The average momentum of a molecule in a sample of an ideal gas depends on
A sample of 0.177 g of an ideal gas occupies 1000 cm3 at STP. Calculate the rms speed of the gas molecules.
Let Q and W denote the amount of heat given to an ideal gas and the work done by it in an isothermal process.
A rigid container of negligible heat capacity contains one mole of an ideal gas. The temperature of the gas increases by 1° C if 3.0 cal of heat is added to it. The gas may be
(a) helium
(b) argon
(c) oxygen
(d) carbon dioxide
An amount Q of heat is added to a monatomic ideal gas in a process in which the gas performs a work Q/2 on its surrounding. Find the molar heat capacity for the process
An ideal gas is taken through a process in which the pressure and the volume are changed according to the equation p = kV. Show that the molar heat capacity of the gas for the process is given by `"C" ="C"_"v" +"R"/2.`
An ideal gas (Cp / Cv = γ) is taken through a process in which the pressure and the volume vary as p = aVb. Find the value of b for which the specific heat capacity in the process is zero.
Two ideal gases have the same value of Cp / Cv = γ. What will be the value of this ratio for a mixture of the two gases in the ratio 1 : 2?
Half mole of an ideal gas (γ = 5/3) is taken through the cycle abcda, as shown in the figure. Take `"R" = 25/3"J""K"^-1 "mol"^-1 `. (a) Find the temperature of the gas in the states a, b, c and d. (b) Find the amount of heat supplied in the processes ab and bc. (c) Find the amount of heat liberated in the processes cd and da.
The volume of an ideal gas (γ = 1.5) is changed adiabatically from 4.00 litres to 3.00 litres. Find the ratio of (a) the final pressure to the initial pressure and (b) the final temperature to the initial temperature.
Consider a given sample of an ideal gas (Cp/Cv = γ) having initial pressure p0 and volume V0. (a) The gas is isothermally taken to a pressure p0/2 and from there, adiabatically to a pressure p0/4. Find the final volume. (b) The gas is brought back to its initial state. It is adiabatically taken to a pressure p0/2 and from there, isothermally to a pressure p0/4. Find the final volume.
Two vessels A and B of equal volume V0 are connected by a narrow tube that can be closed by a valve. The vessels are fitted with pistons that can be moved to change the volumes. Initially, the valve is open and the vessels contain an ideal gas (Cp/Cv = γ) at atmospheric pressure p0 and atmospheric temperature T0. The walls of vessel A are diathermic and those of B are adiabatic. The valve is now closed and the pistons are slowly pulled out to increase the volumes of the vessels to double the original value. (a) Find the temperatures and pressures in the two vessels. (b) The valve is now opened for sufficient time so that the gases acquire a common temperature and pressure. Find the new values of the temperature and pressure.
The figure shows an adiabatic cylindrical tube of volume V0 divided in two parts by a frictionless adiabatic separator. Initially, the separator is kept in the middle, an ideal gas at pressure p1 and temperature T1 is injected into the left part and another ideal gas at pressure p2 and temperature T2 is injected into the right part. Cp/Cv = γ is the same for both the gases. The separator is slid slowly and is released at a position where it can stay in equilibrium. Find (a) the volumes of the two parts (b) the heat given to the gas in the left part and (c) the final common pressure of the gases.
A cubic vessel (with faces horizontal + vertical) contains an ideal gas at NTP. The vessel is being carried by a rocket which is moving at a speed of 500 ms–1 in vertical direction. The pressure of the gas inside the vessel as observed by us on the ground ______.
Diatomic molecules like hydrogen have energies due to both translational as well as rotational motion. From the equation in kinetic theory `pV = 2/3` E, E is ______.
- the total energy per unit volume.
- only the translational part of energy because rotational energy is very small compared to the translational energy.
- only the translational part of the energy because during collisions with the wall pressure relates to change in linear momentum.
- the translational part of the energy because rotational energies of molecules can be of either sign and its average over all the molecules is zero.
In a diatomic molecule, the rotational energy at a given temperature ______.
- obeys Maxwell’s distribution.
- have the same value for all molecules.
- equals the translational kinetic energy for each molecule.
- is (2/3)rd the translational kinetic energy for each molecule.
