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What happens when ammonia solution is added first dropwise and then in excess to the following solution: CuSO4 Write balanced equation for these reaction. - Chemistry

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प्रश्न

What happens when ammonia solution is added first dropwise and then in excess to the following solution:

CuSO4

Write a balanced equation for this reaction.

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उत्तर

\[\ce{\underset{\text{blue}}{CuSO4} + 2NH4OH -> \underset{\text{pale blue ppt.}}{Cu(OH)2\downarrow} + \underset{\text{colourless in solution}}{(NH4)2SO4}}\]

With excess of NH4OH , ppt. dissolves

\[\ce{Cu(OH)2 + 4NH4OH -> \underset{(Deep Blue Solution)}{\underset{Tetrammine copper (II) hydroxide}{[Cu(NH3)4](OH2)}} + 4H2O}\]

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Action of Ammonium Hydroxide on Certain Salt Solutions
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