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प्रश्न
Name the method used for preparation of the following salt from the list given below:
Zinc ion and Lead ion.
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उत्तर
Zinc ion and Lead ion.
(i) \[\ce{ZnSO4 + 2NH4OH -> Zn(OH)2 v + (NH4)2SO4}\]
Zn(OH)2 forms white gelatinous precipitates. In the presence of excess of ammonium hydroxide these precipitates get dissolved.
(ii) \[\ce{Pb(NO3)2 + 2NH4OH -> Pb(OH)2 v + 2NH4NO3}\]
Pb(OH)2 forms white precipitates. This precipitate is insoluble in the presence of excess of ammonium hydroxide.
Concept Insight : Ammonium hydroxide forms insoluble hydroxides when treated with certain metallic salt solution. The insoluble hydroxides thus formed get precipitated in the form of a precipitate and may be identified by their distinct colours.
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संबंधित प्रश्न
Choose the correct answer from the options given below:
A chloride which forms a precipitate that is soluble in excess of ammonium hydroxide is:
1) Calcium chloride
2) Ferrous chloride
3) Ferric chloride
4) Copper chloride
What happens when ammonia solution is added first dropwise and then in excess to the following solution:
ZnSO4
Write a balanced equation for this reaction.
Three test tubes contain calcium nitrate solution, zinc nitrate solution and lead nitrate solution.Describe the effect of Adding ammonium hydroxide to each portion in turn till it is in excess.
Write the observation for the following:
NaOH is added drop-wise till in excess to a solution of zinc sulphate.
The following table shows the tests a student performed on four different aqueous solutions which are X,Y,Z and W. Based on the observations provided, Identify the cation present
|
Chemical Test |
Observation | Conclusion |
| To Solution X, ammonium hydroxide is added in minium quantity first and then in excess | A dirty white precipitate is formed which dissolves in excess to form a clear solution | (i) |
| To Solution Y, ammonium hydroxide is added in minimum quantity first and then in excess | A pale blue precipitate is formed which dissolves in excess to form a clear inky blue solution | (ii) |
| To solution W, A small quantity of sodium hydroxide solution is added and then in excess | A white precipitate is formed which remains insoluble | (iii) |
| To a salt Z, calcium hydroxide solution is added and then heated | A pungent smelling gas turning moist red litmus paper blue is obtained | (iv) |
Identify the cation of the following case:
NaOH solution when added to solution (A) gives a reddish brown precipitate
Write balanced equation copper sulphate solution with ammonium hydroxide solution.
Write balanced equation :
Copper sulphate solution with ammonium hydroxide solution.
Rita was given an unknown salt for identification. She prepared a solution of the salt and divided it into two parts.
- To the first part of the salt solution, she added a few drops of ammonium hydroxide and obtained a reddish-brown precipitate.
- To the second part of the salt solution, she added a few drops of silver nitrate solution and obtained a white precipitate.
Name:
- The cation present and
- The anion present in the salt given for identification.
Write balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
