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प्रश्न
Distinguish between the given pair of compounds using the test given within brackets:
A lead salt and a zinc salt (using excess ammonium hydroxide)
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उत्तर
\[\ce{Pb(NO3)2 + 2NH4OH -> \underset{Chalky white ppt.}{Pb(OH)2↓} + 2NH4NO3}\]
Insoluble in excess of NH4OH,
\[\ce{ZnSO4 + 2NH4OH -> \underset{White gelatinous ppt.}{Zn(OH)2↓} + (NH4)2SO4}\]
With the excess of NH4OH ppt. dissolves.
\[\ce{Zn(OH)2 + (NH4)2SO4 + 2NH4OH -> \underset{Tetra amine zinc sulphate}{[Zn(NH3)4]SO4} + 4H2O}\]
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संबंधित प्रश्न
What happens when ammonia solution is added first dropwise and then in excess to the following solution:
CuSO4
Write a balanced equation for this reaction.
Fill in the blank.
The salt which will not react with NH4OH solution ______[ZnCl2, CuCl2 / NH4Cl/ FeCl2]
State what do you observe when:
Ammonium hydroxide is added to iron (III) sulphate solution.
The following table shows the tests a student performed on four different aqueous solutions which are X,Y,Z and W. Based on the observations provided, Identify the cation present
|
Chemical Test |
Observation | Conclusion |
| To Solution X, ammonium hydroxide is added in minium quantity first and then in excess | A dirty white precipitate is formed which dissolves in excess to form a clear solution | (i) |
| To Solution Y, ammonium hydroxide is added in minimum quantity first and then in excess | A pale blue precipitate is formed which dissolves in excess to form a clear inky blue solution | (ii) |
| To solution W, A small quantity of sodium hydroxide solution is added and then in excess | A white precipitate is formed which remains insoluble | (iii) |
| To a salt Z, calcium hydroxide solution is added and then heated | A pungent smelling gas turning moist red litmus paper blue is obtained | (iv) |
What do you observe when caustic soda solution is added to the following solution: first a little and then in excess:
CuSO4
Write a balanced equation for this reaction.
Write balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
______ is a white precipitate that is soluble in excess of Ammonium hydroxide solution.
Write balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
A ______ coloured precipitate is formed when ammonium hydroxide is added to a solution of ferrous chloride.
Write balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
