Advertisements
Advertisements
प्रश्न
If the initial concentration of substance A is 1.5 M and after 120 seconds the concentration of substance A is 0.75 M, the rate constant for the reaction if it follows zero-order kinetics is ______.
विकल्प
0.00625 molL-1s-1
0.00625 s-1
0.00578 molL-1s-1
0.00578 s-1
Advertisements
उत्तर
If the initial concentration of substance A is 1.5 M and after 120 seconds the concentration of substance A is 0.75 M, the rate constant for the reaction if it follows zero-order kinetics is 0.00625 molL-1s-1.
Explanation:
For Zero order reaction,
k = `(["R"]_0 - ["R"])/"t"`
k = `(1.5 - 0.75)/120`
k = 0.00625 molL-1s-1
APPEARS IN
संबंधित प्रश्न
The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table:
| Experiment | A/mol L−1 | B/mol L−1 | Initial rate/mol L−1 min−1 |
| I | 0.1 | 0.1 | 2.0 × 10−2 |
| II | ______ | 0.2 | 4.0 × 10−2 |
| III | 0.4 | 0.4 | ______ |
| IV | ______ | 0.2 | 2.0 × 10−2 |
Derive integrated rate law for a zero-order reaction \[\ce{A -> Product}\].
At high pressure the following reaction is zero order.
\[\ce{2NH3(g) ->[1130 K][Platinum catalyst] N2(g) + 3H2(g)}\]
Which of the following options are correct for this reaction?
(i) Rate of reaction = Rate constant.
(ii) Rate of the reaction depends on concentration of ammonia.
(iii) Rate of decomposition of ammonia will remain constant until ammonia disappears completely.
(iv) Further increase in pressure will change the rate of reaction.
Derive an expression to calculate time required for completion of zero order reaction.
For a zero order reaction will the molecularity be equal to zero? Explain.
A solution with initial concentration of a mol dm-3 follow zero order kinetic. The time taken for the completion of reaction is
The following experimental rate data were obtained for a reaction carried out at 25°C:
\[\ce{A_{(g)} + B_{(g)} -> C_{(g)} + A_{(g)}}\]
| Initial [A(g)]/mol dm−3 | Initial [B(g)]/mol dm−3 | Initial rate/mol dm−3s−1 |
| 3.0 × 10−2 | 2.0 × 10−2 | 1.89 × 10−4 |
| 3.0 × 10−2 | 4.0 × 10−2 | 1.89 × 10−4 |
| 6.0 × 10−2 | 4.0 × 10−2 | 7.56 × 10−4 |
What are the orders with respect to A(g) and B(g)?
Assertion (A): For a zero-order reaction, the unit of rate constant and rate of reaction are same.
Reason (R): Rate of reaction for zero order reaction is independent of concentration of reactant.
What is zeroth order reaction? Derive its integrated rate Law. What are the units of rate constant?
What is zero order reaction?
