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How will the action of dilute hydrochloric acid enable you to distinguish between sodium thiosulphate and sodium sulphite? - Chemistry

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प्रश्न

How will the action of dilute hydrochloric acid enable you to distinguish between sodium thiosulphate and sodium sulphite?

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उत्तर

Sodium thiosulphate reacts with dil. HCl to produce sulphur dioxide gas and precipitates yellow sulphur.

\[\ce{Na2S2O3 + 2HCl → 2NaCl + H2O + SO2 + S↓}\]

Sulphur is not precipitated when sulphites are treated with dil. HCl.

\[\ce{Na2SO3 + 2HCl -> 2NaCl + H2O + SO2 ^}\]

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General Preparation of Hydrogen Chloride Gas
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