Advertisements
Advertisements
प्रश्न
For the first order thermal decomposition reaction, the following data were obtained:
Time / sec Totalpressure / atm
0 0.30
300 0.50
Calculate the rate constant
(Given: log 2 = 0.301, log3 = 0.4771, log 4 = 0.6021)
Advertisements
उत्तर
Given :
Pi = 0.30 atm
Pt = 0.50 atm
C2H5Cl(g)→C2H4(g)+HCl(g)
Pi 0 0 (At t = 0 sec)
Pi-x x x (At t = 300 sec)
So,
Pi - x + x + x = Pt
0.3+x = 0.5
x = 0.2
Then, Pi - x = 0.3 - 0.2 = 0.1 atm
For first order reaction,
`k=2.303/tlog(P_i/(P_i-x))`
`=2.303/tlog(0.3/0.1)`
`=(2.303xxlog3)/300=(2.303xx0.4771)/300`
k = 0.0037 s-1
APPEARS IN
संबंधित प्रश्न
A → B is a first order reaction with rate 6.6 × 10-5m-s-1. When [A] is 0.6m, rate constant of the reaction is
- 1.1 × 10-5s-1
- 1.1 × 10-4s-1
- 9 × 10-5s-1
- 9 × 10-4s-1
The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume :
SO2Cl2 (g) → SO2 (g) + Cl2 (g)
| Experiment | Time/s–1 | Total pressure/atm |
| 1 | 0 | 0.4 |
| 2 | 100 | 0.7 |
Calculate the rate constant.
(Given : log 4 = 0.6021, log 2 = 0.3010)
From the rate expression for the following reaction, determine the order of reaction and the dimension of the rate constant.
\[\ce{C2H5Cl_{(g)} -> C2H4_{(g)} + HCl_{(g)}}\] Rate = k[C2H5Cl]
A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is doubled?
Rate of reaction for the combustion of propane is equal to:
\[\ce{C3H8_{(g)} + 5O2_{(g)} -> 3CO2_{(g)} + 4H2O_{(g)}}\]
A catalyst in a reaction changes which of the following?
The half-life period of a. substance in a certain enzyme catalysed reaction is 138 s. The time required for the concentration of the substance to fall from 1.28 mol–1 to 0.04 mg L–1 is
The conversion of molecules A to B follow second order kinetics. If concentration of A is increased to three times, how will it affect the rate of formation of B?
A drop of solution (volume 0.05 ml) contains 3.0 × 10-6 mole of H+. If the rate constant of disappearance of H+ is 1.0 × 107 mole l-1s-1. It would take for H+ in drop to disappear in ______ × 10-9s.
Which of the following statement is true?
