हिंदी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Assertion: When NaCl is added to water a depression in freezing point is observed. Reason: The lowering of vapour pressure of a solution causes depression in the freezing point. - Chemistry

Advertisements
Advertisements

प्रश्न

Assertion: When NaCl is added to water a depression in freezing point is observed.

Reason: The lowering of vapour pressure of a solution causes depression in the freezing point.

विकल्प

  • Assertion and reason both are correct statements and reason is correct explanation for assertion.

  • Assertion and reason both are correct statements but reason is not correct explanation for assertion.

  • Assertion is correct statement but reason is wrong statement.

  • Assertion and reason both are incorrect statements.

  • Assertion is wrong statement but reason is correct statement.

MCQ
Advertisements

उत्तर

Assertion and reason both are correct statements and reason is correct explanation for assertion.

Explanation:

On addition of non-volatile solute (viz, NaCl) to water: NaCl solution is formed. Due to relatively lesser number of water molecules at the surface of liquid, the solution exerts a lower vapour pressure as compared to that of pure water. It is because of this lowering of vapour pressure that a depression in freezing point of water is observed.

shaalaa.com
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 2: Solutions - Exercises [पृष्ठ २७]

APPEARS IN

एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 2 Solutions
Exercises | Q V. 53. | पृष्ठ २७

संबंधित प्रश्न

Which of the following solutions shows maximum depression in freezing point?

(A) 0.5 M Li2SQ4

(B) 1 M NaCl

(C) 0.5 M A12(SO4)3

(D) 0.5 MBaC12


When 2.56 g of sulphur was dissolved in 100 g of CS2, the freezing point lowered by 0.383 K. Calculate the formula of sulphur (Sx).

(Kf for CS2 = 3.83 K kg mol−1, Atomic mass of sulphur = 32 g mol−1]


Calculate the mass of ascorbic acid (Vitamin C, C6H8O6) to be dissolved in 75 g of acetic acid to lower its melting point by 1.5°C. Kf = 3.9 K kg mol−1.


Give reasons for the following:

Measurement of osmotic pressure method is preferred for the determination of molar masses of macromolecules such as proteins and polymers.


A 4% solution(w/w) of sucrose (M = 342 g mol–1) in water has a freezing point of 271.15 K. Calculate the freezing point of 5% glucose (M = 180 g mol–1) in water.
(Given: Freezing point of pure water = 273.15 K) 


A 4% solution(w/w) of sucrose (M = 342 g mol−1) in water has a freezing point of 271.15 K. Calculate the freezing point of 5% glucose (M = 180 g mol−1) in water.
(Given: Freezing point of pure water = 273.15 K)


Pure benzene freezes at 5.45°C. A 0.374 m solution of tetrachloroethane in benzene freezes at 3.55°C. The Kf for benzene is:


0.01 M solution of KCl and BaCl2 are prepared in water. The freezing point of KCl is found to be – 2°C. What is the freezing point of BaCl2 to be completely ionised?


Which observation(s) reflect(s) colligative properties?

(i) A 0.5 m NaBr solution has a higher vapour pressure than a 0.5 m BaCl2 solution at the same temperature.

(ii) Pure water freezes at a higher temperature than pure methanol.

(iii) A 0.1 m NaOH solution freezes at a lower temperature than pure water.


In comparison to a 0.01 m solution of glucose, the depression in freezing point of a 0.01 m MgCl2 solution is ______.


Calculate freezing point depression expected for 0.0711 m aqueous solution of Na2SO4. If this solution actually freezes at – 0.320°C, what will be the value of van't Hoff factor? (kg for water = 108b°C mol–1)


Of the following four aqueous solutions, total number of those solutions whose freezing points is lower than that of 0.10 M C2H5OH is ______. (Integer answer)

  1. 0.10 M Ba3 (PO4)2
  2. 0.10 M Na2 SO4
  3. 0.10 M KCl
  4. 0.10 M Li3 PO

1000 g of 1 m sucrose solution in water is cooled to −3.534°C. What weight of ice would be separated out at this temperature 1 is ______ gm. Kf(H2O) = 1.86 K mol−1 Kg)


40 g of glucose (Molar mass = 180) is mixed with 200 mL of water. The freezing point of solution is ______ K. (Nearest integer)

[Given : Kf = 1.86 K kg mol-1; Density of water = 1.00 g cm-3; Freezing point of water = 273.15 K]


Out of the following 1.0 M aqueous solution, which one will show the largest freezing point depression?


Ibrahim collected 10 mL each of fresh water and ocean water. He observed that one sample labeled “P” froze at 0° C while the other “Q” at -1.3° C. Ibrahim forgot which of the two, “P” or “Q” was ocean water. Help him identify which container contains ocean water, giving rationalization for your answer.


The depression in freezing point of water observed for the same amount of acetic acid, trichloroacetic acid and trifluoroacetic acid increases in the order given above. Explain briefly.


The depression in freezing point of water observed for the same amount of acetic acid, trichloroacetic acid and trifluoroacetic acid increases in the order given above. Explain briefly.


The depression in freezing point of water observed for the same amount of acetic acid, trichloroacetic acid and trifluoroacetic acid increases in the order given above. Explain briefly.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×