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प्रश्न
Arrange the following:
In increasing order of basic strength:
C6H5NH2, C6H5N(CH3)2, (C2H5)2NH and CH3NH2
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उत्तर
C6H5N(CH3)2 is more basic than C6H5NH2 due to the presence of the +I effect of two −CH3 groups in C6H5N(CH3)2. Further, CH3NH2 contains one −CH3 group while (C2H5)2NH contains two −C2H5 groups. Thus, (C2H5)2NH is more basic than C2H5NH2.
Now, C6H5N(CH3)2 is less basic than CH3NH2 because of the −R effect of −C6H5 group.
Hence, the increasing order of the basic strengths of the given compounds is as follows:
C6H5NH2 < C6H5N(CH3)2 < CH3NH2 < (C2H5)2NH
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संबंधित प्रश्न
Arrange the following:
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Arrange the following:
In decreasing order of basic strength in the gas phase:
C2H5NH2, (C2H5)2NH, (C2H5)3N and NH3
The correct increasing order of basic strength for the following compounds is ______.
(I)
(II)
(III)
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When ethanol is mixed with ammonia and passed over alumina the compound formed is which compound?
By the presence of a halogen atom in the ring, what is the effect of this on basic property of aniline?
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pKb of aniline is lower than the m-nitroaniline.
Among the following, which has the highest value of pKb?
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Alkylamine is soluble in water, whereas arylamine is insoluble in water.
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