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Theory of Electrolytic Dissociation

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  • Theorem: Electrolytic Dissociation
CISCE: Class 10

Theorem: Electrolytic Dissociation

Statement:

Electrolytes, when dissolved in water, dissociate into free ions that help conduct electricity.

Proof / Explanation:

  1. Electrolytes break into cations (+) and anions (−) in water.
  2. These ions carry an electric charge and allow current to flow.
  3. More ions in solution = higher conductivity.
  4. The number of + and − charges stays balanced (electrolytic equilibrium).
  5. Non-electrolytes (like sugar) do not form ions, so they don’t conduct electricity.
  6. The degree of dissociation indicates how much an electrolyte dissociates into ions.

Modern concept:

  • Arrhenius said water causes ionisation.
  • Modern view: Electrolytes are ionic even in solid form, but ions are held tightly.
  • Water breaks these forces, allowing ions to move freely.

Conclusion:

Electrolytes conduct electricity in solution because their ions are free to move. Water enables this movement by breaking ionic forces.

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