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Tamil Nadu Board of Secondary EducationHSC Science Class 11

HSC Science Class 11 - Tamil Nadu Board of Secondary Education Question Bank Solutions for Chemistry

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Chemistry
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Define the calorific value of food.

[7] Thermodynamics
Chapter: [7] Thermodynamics
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What is the unit of calorific value?

[7] Thermodynamics
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Which one of the following binary liquid mixtures exhibits positive deviation from Raoults law?

[9] Solutions
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At 100°C the vapour pressure of a solution containing 6.5 g a solute in 100 g water is 732 mm. If Kb = 0.52, the boiling point of this solution will be ______.

[9] Solutions
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According to Raoults law, the relative lowering of vapour pressure for a solution is equal to ______.

[9] Solutions
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The relative lowering of vapour pressure of a sugar solution in water is 2.5 × 10-3. The mole fraction of water in that solution is ______.

[9] Solutions
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Which of the following aqueous solutions has the highest boiling point?

[9] Solutions
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Explain how heat absorbed at constant volume is measured using a bomb calorimeter with a neat diagram.

[7] Thermodynamics
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The vapour pressure of pure benzene (C6H6) at a given temperature is 640 mm Hg. 2.2 g of non – volatile solute is added to 40 g of benzene. The vapour pressure of the solution is 600 mm Hg. Calculate the molar mass of the solute?

[9] Solutions
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In a constant volume calorimeter, 3.5 g of gas with molecular weight 28 was burnt in excess oxygen at 298 K. The temperature of the calorimeter was found to increase from 298 K to 298.45 K due to the combustion process. Given that the calorimeter constant is 2.5 kJ K−1. Calculate the enthalpy of combustion of the gas in kJ mol−1.

[7] Thermodynamics
Chapter: [7] Thermodynamics
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Calculate the standard heat of formation of propane, if its heat of combustion is −2220.2 kJ mol−1 the heats of formation of \[\ce{CO2_{(g)}}\] and \[\ce{H2O_{(l)}}\] are −393.5 and −285.8 kJ mol−1 respectively.

[7] Thermodynamics
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A gas mixture of 3.67 lit of ethylene and methane on complete combustion at 25°C and at 1 atm pressure produce 6.11 lit of carbon dioxide. Find out the amount of heat evolved in kJ, during this combustion. (ΔHC(CH4)) = − 890 kJ mol−1 and (ΔHC(C2H4)) = − 1423 kJ mol−1

[7] Thermodynamics
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A sample of 0.5 g of an organic compound was treated according to Kjeldahl’s method. The ammonia evolved was absorbed in 50mL of 0.5 M H2SO4 The remaining acid after neutralization by ammonia consumed 80 mL of 0.5 M NaOH. The percentage of nitrogen in the organic compound is.

[11] Fundamentals of Organic Chemistry
Chapter: [11] Fundamentals of Organic Chemistry
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In an organic compound, phosphorus is estimated as ______.

[11] Fundamentals of Organic Chemistry
Chapter: [11] Fundamentals of Organic Chemistry
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Give the principle involved in the estimation of halogen in an organic compound by Carius method.

[11] Fundamentals of Organic Chemistry
Chapter: [11] Fundamentals of Organic Chemistry
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0.30 g of a substance gives 0.88 g of carbon dioxide and 0.54 g of water calculate the percentage of carbon and hydrogen in it.

[11] Fundamentals of Organic Chemistry
Chapter: [11] Fundamentals of Organic Chemistry
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The ammonia evolved form 0.20 g of an organic compound by Kjeldahl method neutralized 15 ml of N/20 sulphuric acid solution. Calculate the percentage of Nitrogen.

[11] Fundamentals of Organic Chemistry
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0.32 g of an organic compound, after heating with fuming nitric acid and barium nitrate crystals is a sealed tube game 0.466 g of barium sulphate. Determine the percentage of sulphur in the compound.

[11] Fundamentals of Organic Chemistry
Chapter: [11] Fundamentals of Organic Chemistry
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0.24g of an organic compound gave 0.287 g of silver chloride in the carius method. Calculate the percentage of chlorine in the compound.

[11] Fundamentals of Organic Chemistry
Chapter: [11] Fundamentals of Organic Chemistry
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In the estimation of nitrogen present in an organic compound by Dumas method 0.35 g yielded 20.7 mL of nitrogen at 15° C and 760 mm pressure. Calculate the percentage of nitrogen in the compound.

[11] Fundamentals of Organic Chemistry
Chapter: [11] Fundamentals of Organic Chemistry
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