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MAH-MHT CET (PCM/PCB) entrance exam Question Bank Solutions for Chemistry

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Chemistry
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Silver crystallizes in face centred cubic structure, if radius of silver atom is 144.5 pm. What is the edge length of unit cell?

[11] Solid State
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Gold crystallizes in face centred cubic structure. If atomic mass of gold is 197 g mol-1, the mass of unit cell of gold is ______.

[11] Solid State
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When a system absorbs 8 kJ of heat and does 2.2 kJ of work on surrounding, calculate the internal energy change.

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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The standard electrode potential of Zn and Ni are - 0.76 V and - 0.25 V respectively. If the reaction takes place in the cell constructed between these two electrodes is spontaneous. What is the standard emf of the cell?

[15] Electrochemistry
Chapter: [15] Electrochemistry
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The major product formed when 2-bromobutane is treated with alcoholic KOH is ______.

[20] Halogen Derivatives
Chapter: [20] Halogen Derivatives
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The order of reactivities of the following alkyl halides for an SN2 reaction is ______.

[20] Halogen Derivatives
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Select the compound which on treatment with nitrous acid liberates nitrogen.

[23] Amines
Chapter: [23] Amines
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Which among the following solid is a non-polar solid?

[19] Coordination Compounds
Chapter: [19] Coordination Compounds
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Which of the following statements is incorrect regarding the dehydrohalogenation of alkenes?

[20] Halogen Derivatives
Chapter: [20] Halogen Derivatives
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12 g of a nonvolatile solute dissolved in 108 g of water produces the relative lowering of vapour pressure of 0.1. The molecular mass of the solute is ______.

[12] Solutions
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A catalyst lowers the activation energy of a certain reaction from 83.314 to 75 kJ mol−1 at 500 K. What will be the rate of reaction as compared to uncatalysed reaction? Assume other things are equal.

[16] Chemical Kinetics
Chapter: [16] Chemical Kinetics
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The order of reactivity of the given haloalkanes towards nucleophiles is:

[20] Halogen Derivatives
Chapter: [20] Halogen Derivatives
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An ideal gas expands against a constant external pressure of 2.0 atmosphere from 20 litre to 40 litre and absorbs 10 kJ of heat from the surrounding. What is the change in the internal energy of the system?

(Given: 1 atm-litre = 101.3 J)

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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Which of the following compounds gives a dye test?

[23] Amines
Chapter: [23] Amines
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The standard EMF for the cell reaction,
\[\ce{Zn + Cu^{2+} -> Zn^{2+} + Cu}\], 
is 1.10 V at 25°C. The EMF of the cell reaction, when 0.1 M Cu2+ and 0.1 M Zn2+ solutions are used at 25°C is:

[15] Electrochemistry
Chapter: [15] Electrochemistry
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Which among the following equation represents Arrhenius equation?

[16] Chemical Kinetics
Chapter: [16] Chemical Kinetics
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The vapour pressure of a solvent A is 0.80 atm. When a non-volatile substance B is added to this solvent its vapour pressure drops to 0.6 atm. the mole fraction of B in the solution is ______.

[12] Solutions
Chapter: [12] Solutions
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Which of the following solutions will have the maximum lowering of vapour pressure at 300 K?

[12] Solutions
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Which of the following in Baeyer's reagent?

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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The compounds [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2 constitutes a pair of ______.

[19] Coordination Compounds
Chapter: [19] Coordination Compounds
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