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MAH-MHT CET (PCM/PCB) entrance exam Question Bank Solutions for Chemistry

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Chemistry
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What is the standard emf of the following cell?

\[\ce{Ni_{(s)} | Ni^{2+}_{( aq)} || Au^{3+}_{( aq)} | Au_{(s)}}\]

if \[\ce{E^0_{Ni}}\] = −0.25 V, \[\ce{E^0_{Au}}\] = 1.50 V.

[15] Electrochemistry
Chapter: [15] Electrochemistry
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Which among the following is correct when energy of activation, Ea of the catalyzed reaction decreases at constant temperature and for same concentration?

[16] Chemical Kinetics
Chapter: [16] Chemical Kinetics
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What is the highest oxidation state exhibited by actinoids?

[18] Transition and Inner Transition Elements
Chapter: [18] Transition and Inner Transition Elements
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Which cation from following does NOT form colourless compound?

(Atomic number - Cu = 29, Ti = 22, Zn = 30, Sc = 21)

[18] Transition and Inner Transition Elements
Chapter: [18] Transition and Inner Transition Elements
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The complex ions [Co(H2O)5(ONO)]2+ and [Co(H2O)5NO2]2+ are ____________.

[19] Coordination Compounds
Chapter: [19] Coordination Compounds
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1 mol of CO2 contains ____________.

[11] Solid State
Chapter: [11] Solid State
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Which one of the following methods is NOT used for the synthesis of amines?

[23] Amines
Chapter: [23] Amines
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\[\ce{Dimethylamine + Benzoyl chloride ->[Pyridine] ?}\]

Product formed is:

[23] Amines
Chapter: [23] Amines
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The formula of two complexes X and Y of chromium are given below:

\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]

X and Y are examples of ____________ isomers.

[19] Coordination Compounds
Chapter: [19] Coordination Compounds
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Which of the following is INCORRECT?

[11] Solid State
Chapter: [11] Solid State
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Which of the following has zero dipole moment?

[19] Coordination Compounds
Chapter: [19] Coordination Compounds
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Which of the following is INCORRECT expression in terms of vapour pressure of pure solvent `("P"_1^0)` and that of solution (P)?

[12] Solutions
Chapter: [12] Solutions
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When C2H5Br is treated with excess of alc. NH3, the major product obtained is ____________.

[20] Halogen Derivatives
Chapter: [20] Halogen Derivatives
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What is the ΔG0 for the following reaction?

\[\ce{Al_{(s)} + Fe^{3+}_{( aq)} -> Al^{3+}_{( aq)} + Fe_{(s)}}\]; \[\ce{E^0_{cell}}\] = +2.43

[15] Electrochemistry
Chapter: [15] Electrochemistry
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The vapour pressure of water at 20°C is 17 mm Hg. The vapour pressure of solution containing 2.8 g urea in 50 g of water is ____________.

[12] Solutions
Chapter: [12] Solutions
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The SN2 reaction of a compound containing an asymmetric carbon atom always gives ____________.

[20] Halogen Derivatives
Chapter: [20] Halogen Derivatives
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For the following cell, standard potential of copper electrode is 0.337 V and standard cell potential is 0.463 V.

\[\ce{Cu | Cu^{2+} (1 M) || Ag^+ (1 M)  Ag}\]

What is the standard potential of silver electrode?

[15] Electrochemistry
Chapter: [15] Electrochemistry
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Atoms of elements A and B crystallize in hep lattice to form a molecule. Element A occupies 2/3 of tetrahedral voids, the formula of molecule is ______.

[11] Solid State
Chapter: [11] Solid State
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Copper crystallizes as face centered cubic lattice, with edge length of unit cell 361 pm. Calculate the radius of copper atom.

[11] Solid State
Chapter: [11] Solid State
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Which of the following changes will cause increase in vapour pressure of 1 molal aqueous KI solution at same temperature?

[12] Solutions
Chapter: [12] Solutions
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