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MAH-MHT CET (PCM/PCB) entrance exam Question Bank Solutions for Chemistry

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Chemistry
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What is the potential of a half-cell consisting of zinc electrode in 0.01 M ZnSO4 solution at 25°C (E0 = −0.763 V)?

[4] Redox Reactions
Chapter: [4] Redox Reactions
Concept: undefined >> undefined

The formation of aldehyde from an alkyl cyanide using SnCl2/conc.HCl is known as ____________.

[22] Aldehydes, Ketones, and Carboxylic Acids
Chapter: [22] Aldehydes, Ketones, and Carboxylic Acids
Concept: undefined >> undefined

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Identify the metal and its atomic number which has an electronic configuration of [Xe]6s1.

[2] Structure of Atom
Chapter: [2] Structure of Atom
Concept: undefined >> undefined

For the electrochemical cell:

\[\ce{M | M+ || X- | X}\]; 

\[\ce{E^{\circ}_{{M^{+}/{M}}}}\] = 0.44 V,

\[\ce{E^{\circ}_{X/X^-}}\] = 0.33 V

Which of the following is TRUE for this data?

[15] Electrochemistry
Chapter: [15] Electrochemistry
Concept: undefined >> undefined

The conjugate acid of \[\ce{HSO^-_4}\] is ____________.

[13] Ionic Equilibrium
Chapter: [13] Ionic Equilibrium
Concept: undefined >> undefined

When heat is released during the reaction, it is denoted as ____________ and when work is done on the system by the surroundings, it is denoted as ____________.

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
Concept: undefined >> undefined

Calculate the amount of work done in bar dm3 when 2 moles of an ideal gas expands isothermally from a volume of 155 dm3 to 200 dm3 against a constant external pressure of 1 bar.

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
Concept: undefined >> undefined

Phenol reacts with concentrated nitric acid in the presence of cone. H2SO4 to form ____________.

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
Concept: undefined >> undefined

The unit of Henry's law constant is ____________.

[12] Solutions
Chapter: [12] Solutions
Concept: undefined >> undefined

In the formation of an aldol, α-carbon atom of one aldehyde molecule attaches to ____________ of another aldehyde molecule.

[22] Aldehydes, Ketones, and Carboxylic Acids
Chapter: [22] Aldehydes, Ketones, and Carboxylic Acids
Concept: undefined >> undefined

If 'I' stands for the distance between the electrodes and 'a' stands for the area of cross-section of the electrode, `"l"/"a"` refers to ____________.

[15] Electrochemistry
Chapter: [15] Electrochemistry
Concept: undefined >> undefined

Number of oxygen atoms present in salicylaldehyde are ______.

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
Concept: undefined >> undefined

\[\ce{C3H8O ->[KMnO4][(Oxidation)] C3H6O2}\]

The compound C3H8O is a/an ____________.

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
Concept: undefined >> undefined

A solution of CuSO4 is electrolysed using a current of 1.5 amperes for 10 minutes. What mass of Cu is deposited at cathode? [Atomic mass of Cu = 63.7]

[15] Electrochemistry
Chapter: [15] Electrochemistry
Concept: undefined >> undefined

Which of the following reaction proves the chlorinating property of phosphorus pentachloride?

[20] Halogen Derivatives
Chapter: [20] Halogen Derivatives
Concept: undefined >> undefined

Which of the following pairs of aryl halides cannot be prepared directly by electrophilic substitution?

[20] Halogen Derivatives
Chapter: [20] Halogen Derivatives
Concept: undefined >> undefined

Using the standard electrode potentials given below, identify the correct statements from the following:

\[\ce{Fe^2+ + 2e^- -> Fe}\]; E0 = −0.44 V

\[\ce{Cu^2+ + 2e^- -> Cu}\]; E0 = +0.34 V

\[\ce{Ag^+ + e^- -> Ag}\]; E0 = +0.80 V

(I) Copper can displace iron from FeSO4 solution

(II) Iron can displace copper from CuSO4 solution

(III) Silver can displace copper from CuSO4 solution

(IV) Iron can displace silver from AgNO3 solution

[4] Redox Reactions
Chapter: [4] Redox Reactions
Concept: undefined >> undefined

Identify compound 'B' in following series of reactions?

\[\ce{Acetonitrile ->[Na/alcohol] A ->[NaNO2/dil.HCI] B}\]

[23] Amines
Chapter: [23] Amines
Concept: undefined >> undefined

Catalyst used in Rosenmund reduction is ____________.

[22] Aldehydes, Ketones, and Carboxylic Acids
Chapter: [22] Aldehydes, Ketones, and Carboxylic Acids
Concept: undefined >> undefined

An acylchloride is hydrogenated over catalyst palladium on barium sulphate to form an aldehyde. This reaction is called as ______.

[22] Aldehydes, Ketones, and Carboxylic Acids
Chapter: [22] Aldehydes, Ketones, and Carboxylic Acids
Concept: undefined >> undefined
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